Hernandez-Niño, Jhon SebastianGuevara, DanielaShamsurin, MaximBenassi, EnricoSokolov, Maxim N.Feliz Rodriguez, Marta2024-06-172024-06-172023-11-070020-1669https://riunet.upv.es/handle/10251/205210[EN] Octahedral tantalum clusters are redox-active compounds. [{Ta6Bri12}Bra2(H2O)a4]·4H2O (i = inner; a = apical ligands) cluster results in efficient pre-catalyst for the light-driven H2 production from aqueous protons in homogeneous conditions. The most active cluster species are in situ generated by apical ligand exchange reaction from aqueous media.Reconocimiento (by)AlcoholsCluster chemistryEvolution reactionsHydrogenMetal clustersArtículo10.1021/acs.inorgchem.3c03045Abierto37935006PMC1066406907.- Asegurar el acceso a energías asequibles, fiables, sostenibles y modernas para todos