Iglesia, María JoseBlandez, Juan F.Fructos, Manuel R.Prieto, AuxiliadoraAlvarez, EleuterioBelderrain, Tomas R.Nicasio, M. Carmen2020-09-182020-09-182012-09-100276-7333https://riunet.upv.es/handle/10251/150306[EN] A novel bis-styrene IPrNi0 derivative has been synthesized from the reaction of Ni(COD)2 and free 1,3-bis(2,6-diisopropylphenyl)imidazolidene (IPr) ligand in the presence of styrene. The complex has been characterized by spectroscopic data as well as by X-ray crystallography. Its catalytic performance in the amination reaction of aryl tosylates is also reported. The catalytic reactions proceed in a very selective manner, affording moderate to high yields of cross-coupling products in short reaction times at 110 °C.Reserva de todos los derechosQUIMICA ORGANICAArtículo10.1021/om300566mCerrado