Sastre Navarro, German Ignaciovan den Bergh, JohanKapteijn, FreekDenysenko, DmytroVolkmer, Dirk2016-09-202016-09-2020141477-9226https://riunet.upv.es/handle/10251/70157The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses to CO2 and N-2.Reconocimiento (by)Metal-organic frameworksAdsorptionUnveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic frameworkArtÃculo10.1039/c4dt00365aAbierto