[EN] In this work, an MWW-type zeolite with pillars containing silicon and niobium oxide was synthesized to obtain a hierarchical zeolite. The effect of niobium insertion in the pillaring process was determined by combining ...
Erigoni, Andrea; Paul, Geo; Meazza, Marta; Hernández Soto, María Consuelo; Miletto, Ivana; Rios, Ramon; Segarra-Almela, Mª De La Candelaria; Marchese, Leonardo; Raja, Robert; Rey Garcia, Fernando; Gianotti, Enrica; DÍAZ MORALES, URBANO MANUEL(The Royal Society of Chemistry, 2019-11-21)
[EN] Two different heterogeneous catalysts carrying aryl-sulfonic moieties, in which the aromatic ring was either fluorinated or not, were successfully synthesized. The multi-step synthetic approaches implemented involved ...
[EN] The catalytic activity of "pyrrolidine type" fragments included or anchored in the mesoporous silica supports or polymeric frameworks have been fully reported for enantioselective transformation. Nevertheless, low ...
[EN] A series of organic-inorganic hybrid bifunctional organosiliceous catalysts with accessible pendant amine groups as single basic sites (such as propylamine, diethylamine, pyrrolidine) and Pd nanoparticles was prepared ...
Gaona Cordero, Aide(Universitat Politècnica de València, 2014-10-22)
[EN] Study of the capacity of bridged silsesquioxanes to be used as effective organic-inorganic precursors,
through differente synthesis procedures, to generate several hybrid porous materiales is shown by the
use of ...
Díaz Morales, Urbano Manuel; Brunel, Daniel; Corma Canós, Avelino(Royal Society of Chemistry, 2013)
[EN] Organic inorganic hybrid materials with different levels of structuration and porous hierarchy and one or several types of active sites in the framework can catalyze multistep chemical processes in a one-pot reactor ...
[EN] Titanosilicate ferrierite zeolite (FER) and its delaminated form (ITQ-6), with various Si/Ti molar ratios, were synthetized and tested as catalysts for diphenyl sulfide (Ph2S) and dimethyl sulfide (DMS) oxidation with ...
[EN] The catalytic performance of Fe-catalysts in selective catalytic reduction of nitrogen oxides with ammonia (NH3-SCR) strongly depends on the nature of iron sites. Therefore, we aimed to prepare and investigate the ...
[EN] In the presented manuscript an influence of the mesoporosity generation in commercial ZSM-5 zeolite on its catalytic performance in two environmental processes, such as NO reduction with ammonia (NH3SCR, Selective ...
[EN] The application of layered zeolites of MWW topology in environmental catalysis has attracted growing attention in recent years; however, only a few studies have explored their performance in selective catalytic reduction ...
Llopis-Perez, Sebastian; Garcia Fernandez, Maria Teresa; Cantin, A.; Velty, Alexandra; Díaz Morales, Urbano Manuel; Corma Canós, Avelino(The Royal Society of Chemistry, 2018-11-11)
[EN] A new chiral mesoporous hybrid material was synthesized based on pyrrolidine units included in a siliceous framework, HybPyr, and integrated into the organic-inorganic structure, from a specific bis-silylated precursor. ...
Zeolites with MWW topology (MCM-22, ITQ-2, and MCM-36) exchanged with copper and iron were studied as catalysts for selective catalytic reduction of NO with ammonia. It was shown that delamination and pillaring of layered ...
[EN] The chemistry between layered MWW zeolite and carbon black pearls (BP 2000) as an inexpensive hard template was investigated to develop a rational one-pot synthesis of MCM-22 microspheres. The characterization results ...
[EN] Understanding the interactions that govern the photophysical behaviour of Metal-organic frameworks (MOFs) and their composites is paramount for their photochemical and photonic applications. In this work, we report ...
Gianotti, Enrica; Díaz Morales, Urbano Manuel; Velty, Alexandra; Corma Canós, Avelino(Royal Society of Chemistry, 2013)
[EN] Bifunctional mesoporous hybrid materials, containing both proton sponges and acid groups, have been prepared following different synthetic routes: co-condensation processes (sol-gel or micellar one-pot routes) or ...
Sepulveda Gutierrez, Eliana(Universitat Politècnica de València, 2020-11-25)
[ES] La química verde, cuyos procesos fueron definidos por Paul Anastas y John Warner, intenta definir procesos químico más amigables con el medio ambiente mediante el cumplimiento de ciertos principios, entre los que se ...
Poli ., Evelyne; Merino Marcos, Estibaliz; Díaz Morales, Urbano Manuel; Brunel, Daniel; Corma Canós, Avelino(American Chemical Society, 2011)
Organosilica materials with different contents of
Tr¿oger¿s base (TB) as builder moieties have been synthesized
from previously synthesized bis-trialkoxysilylated Tr¿oger¿s base.
Three well-nanostructured hybrid mesoporous ...
Nafria, Raquel; Ramirez de la Piscina, Pilar; Homs, Narcis; Ramon Morante, Joan; Cabot, Andreu; Díaz Morales, Urbano Manuel; Corma Canós, Avelino(Royal Society of Chemistry, 2013)
The ability to produce catalytic nanoparticles with controlled properties is key to developing and producing heterogeneous catalysts with optimized activity and selectivity. No less important is to maximize the nanoparticle ...
Prieto Arnal, Alejandro(Universitat Politècnica de València, 2014-09-25)
[EN] Several bi-functional materials based in palladium nanoparticles supported onto nanocrystalline
titanium silicalite zeolite (Pd@TS-1) were prepared and used as active and reusable catalysts to direct
PO production ...
[EN] Different metalorganic lamellar hybrid materials based on associated nanoribbons were synthesized by the use of alkyl-benzyl monocarboxylate spacers, containing alkyl tails with variable lengths, which acted like ...