[EN] The catalytic activity of "pyrrolidine type" fragments included or anchored in the mesoporous silica supports or polymeric frameworks have been fully reported for enantioselective transformation. Nevertheless, low ...
Velty, Alexandra; Corma Canós, Avelino(The Royal Society of Chemistry, 2023-03-06)
[EN] For many years, capturing, storing or sequestering CO2 from concentrated emission sources or from air has been a powerful technique for reducing atmospheric CO2. Moreover, the use of CO2 as a C1 building block to ...
Llopis-Perez, Sebastian; Garcia Fernandez, Maria Teresa; Cantin, A.; Velty, Alexandra; Díaz Morales, Urbano Manuel; Corma Canós, Avelino(The Royal Society of Chemistry, 2018-11-11)
[EN] A new chiral mesoporous hybrid material was synthesized based on pyrrolidine units included in a siliceous framework, HybPyr, and integrated into the organic-inorganic structure, from a specific bis-silylated precursor. ...
Gianotti, Enrica; Díaz Morales, Urbano Manuel; Velty, Alexandra; Corma Canós, Avelino(Royal Society of Chemistry, 2013)
[EN] Bifunctional mesoporous hybrid materials, containing both proton sponges and acid groups, have been prepared following different synthetic routes: co-condensation processes (sol-gel or micellar one-pot routes) or ...
[EN] Different metalorganic lamellar hybrid materials based on associated nanoribbons were synthesized by the use of alkyl-benzyl monocarboxylate spacers, containing alkyl tails with variable lengths, which acted like ...
Moreno, José María; Velty, Alexandra; Vidal Moya, José Alejandro; DÍAZ MORALES, URBANO MANUEL; Corma Canós, Avelino(The Royal Society of Chemistry, 2018-04-21)
[EN] Novel aluminium MOF-type materials structured by 1D subdomains, such as organic-inorganic nanoribbons, were synthesized by modifying the conditions of solvothermal synthesis and the nature of the solvents in the ...
Coloma-Molina, Alicia; Velty, Alexandra; Díaz, Urbano(The Royal Society of Chemistry, 2023-03-27)
[EN] We present the one-pot synthesis of functionalized organosilica nanoparticles to generate multi-functional hybrid catalysts. Octadecyl, alkyl-thiol and alkyl-amino moieties were used separately and in different ...
[EN] Three families of organosiliceous materials with different structuration level, order, and textural properties (non-ordered, M41S, and SBA-15 type materials) were prepared incorporating in their structural framework ...
Sala Huedo, Gabriela(Universitat Politècnica de València, 2023-11-03)
[ES] En estos últimos años la química sostenible y su aplicación en los procesos químicos ha
ido cobrando cada vez más importancia. Para cumplir con esto, cada día se buscan nuevas
rutas de síntesis más sostenibles y con ...
Gaona Cordero, Aide; Moreno, José María; Velty, Alexandra; Díaz Morales, Urbano Manuel; Corma Canós, Avelino(Royal Society of Chemistry, 2014)
Layered hybrid materials (LHMs) based on ordered silicoaluminate sheets linked with organic fragments, perpendicularly located and stabilized in the interlayer space, were synthesized by a one-pot direct hydrothermal process ...
Glycerol carbonate esters (GCEs), which are valuable biomass-deriv. compds., have been prepd. through the direct esterification of glycerol carbonate and long org. acids with different chain lengths, in the absence of ...
Puche Panadero, Marta; Velty, Alexandra(The Royal Society of Chemistry, 2019-08-21)
[EN] Different Ti-beta zeolite samples were prepared following a convenient and optimized post-synthetic route and starting from commercial Al-beta zeolite. Lewis acid sites have been successfully incorporated into vacant ...
[EN] 1,8-Bis(tetramethylguanidino)naphthalene (TMGN), a neutral organic base that combines the properties of guanidine and the properties of proton sponges, was used as a building block to produce organicinorganic silica-based ...
Moreno-Rodríguez, José María; Velty, Alexandra; DÍAZ MORALES, URBANO MANUEL; Corma Canós, Avelino(The Royal Society of Chemistry, 2019-02-21)
[EN] Novel MOF-type materials with different morphologies based on assembled 1D organic-inorganic subdomains were prepared using specific monodentate benzylcarboxylate spacers with functional substituents in the para-position ...
[EN] 5-hydroxymethylfurfural (HMF) is one of the most valuable biomass platform molecules, enabling the construction of a plethora of high value-added furanic compounds. In particular, in the last decade, HMF has been ...
Subbotina, Elena; Velty, Alexandra; Samec, Joseph S. M.; Corma Canós, Avelino(John Wiley & Sons, 2020-09-07)
[EN] Organosolv pulping releases reactive monomers from both lignin and hemicellulose by the cleavage of weak C-O bonds. These monomers recombine to form undesired polymers through the formation of recalcitrant C-C bonds. ...