[EN] Copper-containing MOFs are found to be active, stable and reusable solid catalysts for three-component couplings of amines, aldehydes and alkynes to form the corresponding propargylamines. Two tandem reactions, including ...
Luz Mínguez, Ignacio(Universitat Politècnica de València, 2011-12-20)
Los metal-organic frameworks (MOFs) son una nueva familia de sólidos porosos que cuentan con una estructura cristalina bien definida. Estos materiales demuestran tener las características apropiadas para ser empleados como ...
Luz Mínguez, Ignacio; Corma Canós, Avelino; Llabrés i Xamena, Francesc Xavier(Royal Society of Chemistry, 2014)
MOFs with Cu2+ centers linked to four nitrogen atoms from azaheterocyclic compounds, i.e., pyrimidine
[Cu(2-pymo)2] and imidazole [Cu(im)2], are active, stable and reusable catalysts for oxidative C O
coupling reactions ...
Epp, Konstantin; Luz, Ignacio; Heinz, Werner R.; Rapeyko, Anastasia; Llabrés i Xamena, Francesc Xavier; Fischer, Roland A.(John Wiley & Sons, 2020-03-19)
[EN] Ruthenium MOF [Ru-3(BTC)(2)Y-y] . G(g) (BTC=benzene-1,3,5-tricarboxylate; Y=counter ions=Cl-, OH-, OAc-; G=guest molecules=HOAc, H2O) is modified via a mixed-linker approach, using mixtures of BTC and pyridine-3,5-d ...
Luz Mínguez, Ignacio(Universitat Politècnica de València, 2015-03-30)
Esta tesis doctoral resume nuestros esfuerzos por contribuir al desarrollo de nuevos catalizadores heterogéneos basados en compuestos Metal-Orgánico estructurados (MOFs). Para ello, y con el fin de cubrir un amplio espectro ...
[EN] Composites incorporating two-dimensional nanostructures within polymeric matrices have potential as functional components for several technologies, including gas separation. Prospectively, employing metal-organic ...
Kozachuk, O.; Luz Mínguez, Ignacio; Llabrés i Xamena, Francesc Xavier; Noei, H.; Kauer, M.; Albada, H.B.; Bloch, E.D.; Marler, B.; Wang, Y.M.; Muhler, M.; Fischer, R.A.(Wiley, 2014-07)
A mixed-linker solid-solution approach was employed to modify the metal sites and introduce structural defects into the mixed-valence Ru-II/III structural analogue of the well-known MOF family [M-3(II,II)(btc)(2)] (M= Cu, ...
Kozachuk, Olesia; Luz Mínguez, Ignacio; Llabrés i Xamena, Francesc Xavier; Noei, Heshmat; Kauer, Max; Bauke Albada, H.; Bloch, Eric D.; Marler, Bernd; Wang, Yuemin; Muhler, Martin; Fischer, Roland A.(Wiley, 2014-07-01)
[DE] Das Konzept der “festen Lösungen mit gemischten Linkern” (mixed-linker solid solution concept) ist angewendet worden, um die Metallzentren des gemischtvalenten RuII/III-Analogons der bekannten Familie der [M3II,II(btc)2]-MOFs ...
Luz Mínguez, Ignacio; Roesler, Christoph; Epp, Konstantin; Llabrés i Xamena, Francesc Xavier; Fischer, Roland A.(Wiley, 2015-08)
[EN] Host-guest inclusion properties of UiO-66 and UiO-67 metal-organic frameworks have been studied using ferrocene (FeCp2) as probe molecule. According to variable-temperature solid-state H-1 and C-13 CP-MAS-NMR, two ...
Luz Mínguez, Ignacio; Leon Peris, Adela; Boronat Zaragoza, Mercedes; Llabrés i Xamena, Francesc Xavier; Corma Canós, Avelino(Royal Society of Chemistry, 2013)
[EN] MOFs with Cu2+ centers linked to four nitrogen atoms from azaheterocyclic compounds, i.e., pyrimidine [Cu(2-pymo)(2)] and imidazole [Cu(im)(2)], are active catalysts for aerobic oxidation of activated alkanes, such ...
Juan Alcañiz, Jana; Ferrando-Soria, Jesus; Luz Mínguez, Ignacio; Serra-Crespo, Pablo; Skupien, Emmanuel; Santos, Vera P.; Pardo, Emilio; Llabrés i Xamena, Francesc Xavier; Kapteijn, Freek; Gascon, Jorge(Elsevier, 2013-11)
A new consecutive post-functionalization method has been developed for the inclusion of additional metal functionalities in Metal Organic Frameworks (MOFs) through oxamate as chelating agent. This may result in catalytic ...
Vitillo, Jenny G.; Presti, Davide; Luz, Ignacio; Llabrés i Xamena, Francesc Xavier; Bordiga, Silvia(American Chemical Society, 2020-10-29)
[EN] Imines are important building blocks in organic chemistry. Titanium-based metal-organic framework (MOF) MIL-125-NH2(Ti) can photocatalyze, under visible light and at room temperature, the selective aerobic oxidation ...