Rivero-Crespo, Miguel Ángel; Mon, Marta; Ferrando-Soria, Jesus; Lopes, Christian W.; Boronat Zaragoza, Mercedes; Leyva Perez, Antonio; Corma Canós, Avelino; Hernandez-Garrido, Juan carlos; López-Haro, Miguel; Calvino, Jose J.; Ramos-Fernandez, Enrique V.; Armentano, Donatella; Pardo, Emilio(John Wiley & Sons, 2018-12-21)
[EN] The synthesis and reactivity of single metal atoms in a low-valence state bound to just water, rather than to organic ligands or surfaces, is a major experimental challenge. Herein, we show a gram-scale wet synthesis ...
Negro, Cristina; Bilanin-Artigado, Cristina; Qu, Xiaoni; Oliver-Meseguer, Judit; Ferrando-Soria, Jesus; Leyva Perez, Antonio; Armentano, Donatella; Pardo, Emilio(The Royal Society of Chemistry, 2022-05-05)
[EN] Allylic alcohol epoxidation and dehydrogenation reactivity is distinguished when VO(acac)(2) is used in solution or anchored in a metal-organic framework (MOF). The chemical mechanism depends on the electronic profile ...
[EN] The exact chemical structure of non-crystallising natural products is still one of the main challenges in Natural Sciences. Despite tremendous advances in total synthesis, the absolute structural determination of a ...
[EN] The search for simple, earth-abundant, cheap, and nontoxic metal catalysts able to perform industrial hydrogenations is a topic of interest, transversal to many catalytic processes. Here, we show that isolated FeIII¿O ...
[EN] Metal single-atom catalysts (SACs) promise great rewards in terms of metal atom efficiency. However, the requirement of particular conditions and supports for their synthesis, together with the need of solvents and ...
[EN] Imines are ubiquitous intermediates in organic synthesis, and the metal-mediated imination of alcohols is one of the most direct and simple methods for their synthesis. However, reported protocols lack compatibility ...
Juan Alcañiz, Jana; Ferrando-Soria, Jesus; Luz Mínguez, Ignacio; Serra-Crespo, Pablo; Skupien, Emmanuel; Santos, Vera P.; Pardo, Emilio; Llabrés i Xamena, Francesc Xavier; Kapteijn, Freek; Gascon, Jorge(Elsevier, 2013-11)
A new consecutive post-functionalization method has been developed for the inclusion of additional metal functionalities in Metal Organic Frameworks (MOFs) through oxamate as chelating agent. This may result in catalytic ...