[EN] A series of C2 symmetrical 1:2 Ni:L complexes derived from a-amino amides were studied for the enantioselective addition of dialkylzinc reagents to aldehydes. Different structural elements on the ligands seem to play ...
Valverde, D.; Garcia Bernabe, Abel; Andrio Balado, Andreu; Garcia-Verdugo, Eduardo; Luis Lafuente, Santiago; Compañ Moreno, Vicente(The Royal Society of Chemistry, 2019-08-28)
[EN] The properties of various mixtures of a zwitterionic ionic liquid (ZIs-1) and LiNTf 2, including their conductivity, have been studied showing how they can be adjusted through their molar composition. Conductivity ...
Escorihuela Fuentes, Jorge; Burguete Azcarate, Mª Isabel; Luis Lafuente, Santiago(Royal Society of Chemistry, 2013-04-16)
[EN] Achieving dual stereocontrol in asymmetric reactions using a single enantiomer for the building of the
chiral catalyst or auxiliary is a very important goal in enantioselective synthesis as it eliminates the need for ...
Burguete Azcarate, Mª Isabel; Collado, M.; Escorihuela Fuentes, Jorge; Galindo, F.; Garcia-Verdugo, E.; Luis Lafuente, Santiago; Vicent, M.J.(Elsevier, 2003)
Ni2+ complexes derived from simple -amino amides catalyze very efficiently the addition of Et2Zn to benzaldehyde, giving (S)-1-phenylethanol as the major isomer in most cases (94% yield, 97% ee for R=Bn). The nature of ...
[EN] A series of polymer-supported -amino amides derived from natural amino acids have been easily syn-thesized and fully characterized. Their chiral Zn (II) complexes catalyzed the enantioselective additionof diethylzinc ...
Martí Centelles, Vicente; Luis Lafuente, Santiago(Editorial Universitat Politècnica de València, 2023-03-09)
La determinación estructural de compuestos orgánicos se basa en la aplicación de los fundamentos teóricos de las diferentes técnicas espectroscópicas para la resolución de problemas. En ella los estudiantes analizan distintos ...
[EN] Different crosslinked polystyrene resins containing ionic liquid fragments covalently attached (supported ionic liquid-like phases: SILLPs) have been prepared and their conductivity has been studied by means of ...