[EN] Present paper describes the influence of the incorporation of alkali metal cations (AM = Li, Na, K, Cs; and an AM/V ratio of 0.04) and Na-content (Na/V ratio of 0.02-0.30) in alkali metal promoted V2O5 catalyst on ...
[EN] Hydrothermally prepared Mo-V-Sb mixed oxides doped with alkali metal cations (Li+, Na+, K+, Rb+, or Cs+) show a significantly improved catalytic behavior in the oxidative dehydrogenation of ethane (ODH) compared to ...
Ivars Barceló, Francisco; Solsona Espriu, Benjamin Eduardo; Hernández Morejudo, Selene; López Nieto, José Manuel(Elsevier, 2010-01-30)
[EN] MoVTeNb mixed oxides catalysts have been prepared by a slurry method with different molar compositions (Mo/Te ratio from 2 to 6 and Nb/(V + Nb) ratio from 0 to 0.7) in the synthesis gel leading to different crystalline ...
Massó Ramírez, Amada; Ivars-Barceló, Francisco; López Nieto, José Manuel(Elsevier, 2020-10-01)
[EN] The investigation here presented studies the effect of the synthesis temperature (from 80 to 110 degrees C) and the time (from 1 to 4 days) employed to precipitate catalyst precursors by reflux method, on the ...
Ivars Barceló, Francisco(Universitat Politècnica de València, 2011-06-24)
La presente tesis doctoral muestra un estudio sobre la síntesis y caracterización de bronces basados en óxidos metálicos de Mo y V, para ser empelados como catalizadores en reacciones de oxidación parcial de hidrocarburos ...
Massó Ramírez, Amada(Universitat Politècnica de València, 2017-11-06)
SUMMARY
The current doctoral thesis studies the synthesis of Mo-V-Te-containing mixed metal oxides and the characterization of their physico-chemical and catalytic properties for alkanes selective oxidation reactions, such ...
Solsona Espriu, Benjamin Eduardo; López Nieto, José Manuel; Concepción Heydorn, Patricia; Dejoz, A.; Ivars Barceló, Francisco; Vazquez, M. I.(Elsevier, 2011-05-16)
Ni-W-O mixed oxides were prepared through the evaporation of aqueous solutions of nickel nitrate and ammonium tungstate and calcined in air at 500 degrees C for 2 h. The catalysts were characterized by several techniques ...
[EN] The robustness of one selected Ni-W-O catalyst has been studied in the oxidative dehydrogenation of ethane. This catalyst initially deactivates for the first 10 h online decreasing 15% of its catalytic activity compared ...
López Nieto, José Manuel; Solsona Espriu, Benjamin Eduardo; Concepción Heydorn, Patricia; Ivars Barceló, Francisco; Dejoz, A.; Vazquez, M. I.(Elsevier, 2010-11-17)
[EN] The catalytic properties of MoVTeNbO catalysts during the selective oxidation of short chain alkanes and olefins (C-2-C-4) have been comparatively studied The main reaction products have been ethylene from ethane ...
[EN] This work reports the applicability of reflux to the synthesis of Mo-V-Te-Nb-O metal oxide catalysts for the first time. The well-formed and defined orthorhombic M1 phase, i.e. Te2M20O57 (M = Mo, V, Nb), was found to ...
Ivars Barceló, Francisco; Solsona Espriu, Benjamin Eduardo; Botella Asuncion, Pablo; Soriano Rodríguez, Mª Dolores; López Nieto, José Manuel(Elsevier, 2009-03-30)
[EN] Alkali metal-doped MoVSbO catalysts have been prepared by impregnation of a MoVSbO-mixed oxide (prepared previously by a hydrothermal synthesis) and finally activated at 500 or 600 degrees C in N-2. The catalysts have ...
Ivars Barceló, Francisco; Solsona Espriu, Benjamin Eduardo; Rodriguez-Castellon, Enrique; López Nieto, José Manuel(Elsevier, 2009-02-15)
Nb-free (SbO)(2)M(20)O(56) catalysts (M = Mo, V) presenting pure M1 phase have been prepared by a post-synthesis treatment with hydrogen peroxide of a heat-treated MoVSbO mixed metal oxide catalyst previously prepared by ...
Ivars Barceló, Francisco; Millet, J. M. M.; Blasco Lanzuela, Teresa; Concepción Heydorn, Patricia; Valente, J. S.; López Nieto, José Manuel(Elsevier, 2014-12)
[EN] The effect of activation treatments of K-free and K-MoVSbO bronzes on either their physico-chemical characteristics or catalytic properties for propane partial oxidation have been studied. The as-synthesized materials, ...
Masso Ramírez, Amada; De Arriba-Mateos, Agustín; Ivars Barceló, Francisco; Ykrelef, Adel; Solsona, Benjamín; López Nieto, José Manuel(The Royal Society of Chemistry, 2023-08-14)
[EN] In the present article we show that, although the reflux method is not common for the synthesis of multicomponent MoVTeNbO catalysts, an optimized reflux synthesis of metallic precursors leads to efficient materials ...