Navas Escrig, Javier(Universitat Politècnica de València, 2011-11-28)
En el presente proyecto se ha tratado de estudiar la aplicabilidad de catalizadores heterogéneos basados
en el oro como especie activa en la monolaquilación de aminas mediante el uso de alcoholes a través de
un mecanismo ...
[EN] A one-pot reaction was performed with a nanoparticulated gold catalyst. A secondary amine is formed through N-monoalkylation of a primary amine with an alcohol by a borrowing hydrogen methodology in a three-step ...
[EN] The catalytic activity of gold depends on particle size, with the reactivity increasing as the particle diameter decreases. However, investigations into behaviour in the subnanometre regime (where gold exists as small ...
Navas Escrig, Javier(Universitat Politècnica de València, 2016-05-16)
[EN] During the work done in this thesis, new catalysts based on metallic nanoparticles and clusters supported on materials with different properties have been designed and developed trying to improve their stability and ...
[EN] Palladium on magnesium oxide is able to allow a one-pot reaction to synthesize thioethers from thiols and aldehydes formed in situ from the respective alcohol by means of a borrowing hydrogen method. The reaction is ...
[EN] The mechanism of the oxidative [3+2] cycloaddition of alkenes with anhydrides using oxygen as an oxidant to synthesize gamma-lactones has been studied using a heterogeneous dual copper-manganese-based catalyst. The ...