Poli ., Evelyne; Merino Marcos, Estibaliz; Díaz Morales, Urbano Manuel; Brunel, Daniel; Corma Canós, Avelino(American Chemical Society, 2011)
Organosilica materials with different contents of
Tr¿oger¿s base (TB) as builder moieties have been synthesized
from previously synthesized bis-trialkoxysilylated Tr¿oger¿s base.
Three well-nanostructured hybrid mesoporous ...
[EN] The synthesis of cyclized organic compounds with more than ten atoms (macrocycles) is traditionally based on reversible reactions under highly diluted conditions, typically <0.05¿M, in order to circumvent the formation ...
Poli, Evelyne; Merino Marcos, Estibaliz; Díaz Morales, Urbano Manuel; Brunel, Daniel; Corma Canós, Avelino(Royal Society of Chemistry, 2011)
The porous organosilica framework containing Troger's base (TB) prepared by mild sol-gel synthesis from 2,8-bis-silylated TB precursor contains a mixture of two point attached TB and one point attached TB units, resulting ...
Merino Marcos, Estibaliz; Poli, Evelyne; Díaz Morales, Urbano Manuel; Brunel, Daniel(Royal Society of Chemistry, 2012)
[EN] This manuscript describes the synthesis and structural study of new second generation Hoveyda¿Grubbs catalysts: 1,3-dimesitylacenaphthylenyl- 4,5-imidazolin-2-ylidene (BIAN-NHC) ruthenium isopropoxybenzylidene dichloride ...
Merino Marcos, Estibaliz; Verde-Sesto, Ester; Maya, Eva M.; Iglesias, Marta; Sanchez, Felix; Corma Canós, Avelino(American Chemical Society, 2013-03-26)
[EN] We described the use of one porous polymeric aromatic framework (PPAF) with a 9,9'-spiro-bisfluorene unit as a support in heterogeneous catalysis. The material was functionalized with acid and base active sites and ...