[EN] The gas-phase oxidehydration (ODH) of 1,2-propanediol to propionic acid has been studied as an intermediate step in the multi-step transformation of bio-sourced glycerol into methylmethacrylate. The reaction involves ...
[EN] This paper deals with an investigation of hexagonal W-Nb-O and W-V-Nb-O bronzes as catalysts for the one-pot oxidehydration of glycerol into acrylic acid. In a previous work, we reported that the best yield to acrylic ...
Chieregato, Alessandro(Universitat Politècnica de València, 2016-04-14)
[EN] The project of this Ph.D. thesis is based on a co-supervised collaboration between Università di Bologna, ALMA MATER STUDIORUM (Italy) and Instituto de Tecnología Química, Universitat Politècnica de València ITQ-UPV ...
[EN] Glycerol surplus from biodiesel synthesis still represents a major problem in the biofuel production chain. Meanwhile, those in the acrylic acid market are looking for new processes that are able to offer viable ...
[EN] We report on a study of the key reaction parameters in glycerol oxidehydration into acrylic acid over W-V-Nb mixed oxides with a hexagonal tungsten bronze structure. This investigation demonstrated that the optimal ...
[EN] The design of suitable catalysts for the one-pot conversion of glycerol into acrylic acid (AA) is a complex matter, as only fine-tuning of the redox and acid properties makes it possible to obtain significant yields ...
Soriano Rodríguez, Mª Dolores; Concepción Heydorn, Patricia; López Nieto, José Manuel; Cavani, Fabrizio; Guidetti, Stefania; Trevisanut, C.(Royal Society of Chemistry, 2011)
[EN] In this paper we report on the one-pot transformation of glycerol into acrylic acid, catalyzed by
W/V mixed oxides, with hexagonal tungsten bronze (HTB) structure. The reaction requires two
different catalyst ...
Balestra, Giulia(Universitat Politècnica de València, 2022-07-28)
[ES] El presente trabajo de investigación está centrado en la valorización y la mejora del bioetanol, empleando catalizadores heterogéneos, en un reactor de flujo continuo a escala de laboratorio.
En primer lugar, en los ...