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Listar por autor "García García, Pilar"

Mostrando ítems 1-14 de 14

A powerful chiral counteranion motif for asymmetric catalysis

García García, Pilar; Lay, Frank; Garcia Garcia, Patricia; Rabalakos, Constantinos; List, Benjamin (Wiley, 2009)
Asymmetric epoxidation of electron-deficient olefins

Diez, D.; Nunez, M.G.; Anton, A.B.; García García, Pilar; Moro, R.F.; Garrido, N. M.; Marcos, I.S.; Basabe, P.; Urones, J.G. (Bentham Science Publishers, 2008-08)

[EN] This paper focuses on the latest developments in asymmetric epoxidation of electron-deficient olefins since the review by Porter and Skidmore on chiral ligand-metal peroxide systems, polyamino acid catalysed and ...
Catalytic Transfer Hydrogenation of Biomass-Derived Carbonyls over Hafnium-Based Metal-Organic Frameworks

Rojas-Buzo, Sergio; García García, Pilar; Corma Canós, Avelino (John Wiley & Sons, 2018-01-23)

[EN] A series of highly crystalline, porous, hafnium-based metal-organic frameworks (Hf-MOFs) have been shown to catalyze the transfer hydrogenation reaction of levulinic ester to produce -valerolactone by using isopropanol ...
Domino Elimination/Nucleophilic Addition in the Synthesis of Chiral Pyrrolidines

Flores, M.F.; García García, Pilar; Garrido, N.M.; Marcos, I.S.; Sanz González, Francisca; Díez, D. (American Chemical Society, 2013-06-28)

Polyhydroxylated pyrrolidines have been synthesized in a one-pot procedure by the addition of an organometallic reagent to isoxazolidines obtained by a 1,3- dipolar cycloaddition between nitrones and vinylsulfones. ...
Enantioselective Organocatalytic Reactions with Isatin

Flores, MariFe; Peña, Javier; García García, Pilar; Garrido, Narciso M.; Diez, David (Bentham Science Publishers, 2013-09)

[EN] Isatin and its derivatives have been widely studied due to their biological activities. Recently there has been a renewed interest in the synthesis of new derivatives by use of organocatalysts. This review deals with ...
From isoxazolidines to tetrahydro-1,3-oxazines for the synthesis of chiral pyrrolidines

García García, Pilar (Royal Society of Chemistry, 2012)

[EN] A novel approach for the synthesis of chiral tetrasubstituted pyrrolidines has been developed. The rearrangement of isoxazolidines into tetrahydro-1,3-oxazines using reactive organic bromides is herein described for ...
Hf-based metal-organic frameworks as acid-base catalysts for the transformation of biomass-derived furanic compounds into chemicals

Rojas-Buzo, Sergio; García-García, Pilar; Corma Canós, Avelino (The Royal Society of Chemistry, 2018)

[EN] Hf-based metal-organic frameworks (MOFs) are reported here as heterogeneous catalysts for the highly selective and efficient cross-aldol condensation of biomass-derived furanic carbonyls with acetone under mild reaction ...
MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts

García García, Pilar; Müller, Maike; Corma Canós, Avelino (Royal Society of Chemistry, 2014)

Metal-organic frameworks have recently attracted attention as heterogeneous catalysts due to their high content of metal centres and large surface area and pore volume, along with their impressive topological richness. ...
Multisite organic-inorganic hybrid catalysts for the direct sustainable synthesis of GABAergic drugs

Leyva Perez, Antonio; García García, Pilar; Corma Canós, Avelino (Wiley-VCH Verlag, 2014-08-11)

Multisite organic inorganic hybrid catalysts have been prepared and applied in a new general, practical, and sustainable synthetic procedure toward industrially relevant GABA derivatives. The domino sequence is composed ...
Organic-inorganic supramolecular solid catalyst boosts organic reactions in water

García García, Pilar; Moreno Rodríguez, José María; Díaz Morales, Urbano Manuel; Bruix, Marta; Corma Canós, Avelino (Nature Publishing Group, 2016-02)

[EN] Coordination polymers and metal-organic frameworks are appealing as synthetic hosts for mediating chemical reactions. Here we report the preparation of a mesoscopic metal-organic structure based on single-layer assembly ...
Remarkable Acceleration of Benzimidazole Synthesis and Cyanosilylation Reactions in a Supramolecular Solid Catalyst

Rojas-Buzo, Sergio; García-García, Pilar; Corma Canós, Avelino (John Wiley & Sons, 2017)

[EN] A solid metal organic catalyst with hydrophobic pockets and Lewis acid centers strongly accelerates the reaction rate for organic reactions. This is exemplified for the cyanosilylation of ketones and for the synthesis ...
Síntesis de catalizadores sólidos orgánicos e híbridos orgánicos-inorgánicos y su aplicación

Villoria del Álamo, Beatriz (Universitat Politècnica de València, 2021-02-22)

[ES] En este trabajo de tesis doctoral, la investigación se ha centrado en el desarrollo de diferentes procesos catalíticos heterogéneos empleando materiales híbridos orgánico-inorgánicos porosos (MOFs y sílices funcionalizadas) ...
Síntesis de materiales porosos metal-orgánicos y su aplicación en catálisis heterogénea

Rojas Buzo, Sergio (Universitat Politècnica de València, 2019-11-04)

[ES] En este trabajo de tesis doctoral se ha llevado a cabo la síntesis de diferentes materiales de tipo metal-orgánico (MOFs) para su aplicación en procesos catalíticos heterogéneos en la obtención de productos químicos ...
Zr-MOF-808@MCM-41 catalyzed phosgene-free synthesis of polyurethane precursors

Rojas-Buzo, Sergio; García-García, Pilar; Corma Canós, Avelino (The Royal Society of Chemistry, 2019-01-07)

[EN] In this work, a catalytic method is presented for the synthesis of aromatic carbamates from aromatic amines using dimethyl carbonate instead of phosgene as a green and safe reaction process. Microcrystalline Zr-MOF-808 ...