Aldehydes possess relatively high chemical energy, which is the driving force for disproportionation reactions such as Cannizzaro and Tishchenko reactions. Generally, this energy is wasted if aldehydes are transformed into ...
Orozco-Arboleda, Lina Marcela; Renz, Michael; Corma Canós, Avelino(The Royal Society of Chemistry, 2017)
[EN] The ketonization of aldehydes joins two molecules, with n carbon atoms each, to a ketone with 2n 1 carbon atoms. When
employing cerium oxide as catalyst with nano-sized crystals (<15 nm) the ketone can be obtained ...
Orozco Arboleda, Lina Marcela(Universitat Politècnica de València, 2017-07-31)
This thesis comprises a detailed work on the ketonization of aldehydes. The ketonization reaction joins two aldehyde molecules, with n carbon atoms each, to a ketone with 2n ¿ 1 carbon atoms. The reaction is involved, ...
Corma Canós, Avelino; Orozco Arboleda, Lina Marcela; Renz, Michael(Royal Society of Chemistry, 2013)
[EN] Zirconium Lewis acid sites grafted onto a mesoporous silicate (MCM-41) and zirconium sites incorporated into inorganic-organic MOF materials are employed successfully in the rearrangement of beta-pinene epoxide into ...
Orozco Arboleda, Lina Marcela(Universitat Politècnica de València, 2013-06-26)
[ES] La transposición del epóxido de beta-pineno en mirtanal es estudiado con clústeres y MOFs de zirconio.
Los clústeres son activos pero pierden los actividad con el tiempo. Los MOFs son activos y estables. La
filtración ...