[EN] The catalytic activity of "pyrrolidine type" fragments included or anchored in the mesoporous silica supports or polymeric frameworks have been fully reported for enantioselective transformation. Nevertheless, low ...
Llopis-Perez, Sebastian; Garcia Fernandez, Maria Teresa; Cantin, A.; Velty, Alexandra; Díaz Morales, Urbano Manuel; Corma Canós, Avelino(The Royal Society of Chemistry, 2018-11-11)
[EN] A new chiral mesoporous hybrid material was synthesized based on pyrrolidine units included in a siliceous framework, HybPyr, and integrated into the organic-inorganic structure, from a specific bis-silylated precursor. ...
[EN] Three families of organosiliceous materials with different structuration level, order, and textural properties (non-ordered, M41S, and SBA-15 type materials) were prepared incorporating in their structural framework ...
Llopis Pérez, Sebastián(Universitat Politècnica de València, 2020-10-26)
[ES] La presente Tesis Doctoral se ha centrado en la síntesis de nuevos materiales híbridos en el ámbito de la quiralidad. Se ha estudiado como afecta la estructuración y disposición de los centros activos quirales en la ...