[EN] Isophthalic acid (IPA) has been considered to build metal-organic frameworks (MOFs), owing to its facile availability, unique connection angle-mode, and a wide range of functional groups attached. Constructing ...
Babaryk, Artem A.; Contreras Almengor, Oscar R.; Cabrero-Antonino, Maria; Navalón Oltra, Sergio; García Gómez, Hermenegildo; Horcajada, Patricia(American Chemical Society, 2020-03-16)
[EN] Inorganic semiconductors are extensively considered to be among the most promising materials to convert solar light into electricity or chemical energy owing to their efficiency in the separation of photoinduced ...
[EN] The assumption that oxidative addition is the key step during the cross-coupling reaction of aryl halides has led to the development of a plethora of increasingly complex metal catalysts, thereby obviating in many ...
Melillo, Arianna; Cabrero-Antonino, Maria; Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; Ferrer Ribera, Rosa Belén; García Gómez, Hermenegildo(Elsevier, 2020-12-05)
[EN] The photocatalytic activity of a series of five UiO-66 (M: Zr, Zr/Ti, Zr/Ce, Zr/Ce/Ti, Ce) materials for overall water splitting with generation of hydrogen and oxygen has been herein measured. The most efficient ...
Remiro-Buenamañana, Sonia; Cabrero-Antonino, Maria; Martínez-Guanter, Marcos; Alvaro Rodríguez, Maria Mercedes; Navalón Oltra, Sergio; García Gómez, Hermenegildo(Elsevier, 2019-10-05)
[EN] Titanium containing aminoterephthalate metal organic framework promotes the photocatalytic overall water splitting into H-2 and O-2 at a rate that depends on the presence of Pt, RuOx and CoOx co-catalyst. The best ...
Cabrero Antonino, María(Universitat Politècnica de València, 2021-11-09)
[ES] La presente tesis doctoral se ha basado en el estudio del uso de MOFs como fotocatalizadores para la producción de combustibles solares. Específicamente, los fotocatalizadores basados en MOF se han utilizado para la ...
[EN] A novel microporous two-dimensional (2D) Ni-based phosphonate metal-organic framework (MOF; denoted as IEF-13) has been successfully synthesized by a simple and green hydrothermal method and fully characterized using ...
Cabrero-Antonino, Maria; Albero-Sancho, Josep; García-Vallés, Cristina; Alvaro Rodríguez, Maria Mercedes; Navalón Oltra, Sergio; García Gómez, Hermenegildo(John Wiley & Sons, 2020-12-01)
[EN] Defect engineering in metal-organic frameworks is commonly performed by using thermal or chemical treatments. Herein we report that oxygen plasma treatment generates structural defects on MIL-125(Ti)-NH2, leading to ...
[EN] The production of solar fuels from CO2 is currently attracting increasing interest. Herein we describe the development of a benchmark metal-organic framework (MOF) photocatalyst based on MIL-125(Ti)-NH2 supported ...
Santiago-Portillo, Andrea; Cabrero-Antonino, Maria; Alvaro Rodríguez, Maria Mercedes; Navalón Oltra, Sergio; García Gómez, Hermenegildo(John Wiley & Sons, 2019-07-11)
[EN] This manuscript reports a comparative study of the catalytic performance of gold nanoparticles (NPs) encapsulated within MIL-101(Cr) with or without amino groups in the terephthalate linker. The purpose is to show how ...
[EN] Two novel three-dimensional metal-organic frameworks(MOFs)based on the photoactive pyrene tetraphosphonate ligand and copper(denoted as IEF-8 and IEF-9) have been hydrothermally synthesizedand fully characterized (XRD, ...