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Listar por autor "Greco, Rossella"

Mostrando ítems 1-10 de 10

Acid and Base Water Coexists in a Micro-Structured Ionic Liquid and Catalyzes Organic Reactions in One-Pot

Leyva Perez, Antonio; Bilanin-Artigado, Cristina; Bacic, Matea; Greco, Rossella (John Wiley & Sons, 2022-10-10)

[EN] The most paradigmatic example of antagonist chemical species are protons and hydroxyls, and their coexistence in a liquid system is of high interest. Here we show that commercial ionic liquids stabilize microdroplets ...
Acid Catalysis with Alkane/Water Microdroplets in Ionic Liquids

Greco, Rossella; Lloret, Vicent; Rivero Crespo, Miguel Ángel; Hirsch, Andreas; Doménech-Carbó, Antonio; Abellán Sáez, Gonzalo; Leyva Perez, Antonio (American Chemical Society, 2021-06-28)

[EN] Ionic liquids are composed of an organic cation and a highly delocalized perfluorinated anion, which remain tight to each other and neutral across the extended liquid framework. Here we show that n-alkanes in millimolar ...
Click amidations, esterifications and one¿pot reactions catalyzed by Cu salts and multimetal-organic frameworks (M-MOFs)

Greco, Rossella; Tiburcio, Estefanía; Palomar-De Lucas, Brenda; Ferrando-Soria, Jesús; Armentano, Donatella; Pardo, Emilio; Leyva Perez, Antonio (Elsevier, 2022-04)

[EN] Amides and esters are prevalent chemicals in Nature, industry and academic laboratories. Thus, it is not surprising that a plethora of synthetic methods for these compounds has been developed along the years. However, ...
Clusters and single atoms of Pd and Pt: Synthesis and applications in catalysis and as antitumoral agents

Greco, Rossella (Universitat Politècnica de València, 2021-09-02)

[ES] En esta tesis se han estudiado la síntesis y aplicación de clústeres y átomos metálicos aislados de Pd y Pt. Clústeres y átomos aislados han sido sintetizados siguiendo nuevas metodologías en disolución, sin utilizar ...
Cytotoxic sub-nanometer aqueous platinum clusters as potential antitumoral agents

Greco, Rossella; García-Laínez, Guillermo; Oliver-Meseguer, Judit; Marini, Carlo; Domínguez, Irene; Lopez-Haro, Miguel; Hernandez-Garrido, Juan Carlos; Cerón-Carrasco, José Pedro; Andreu, Inmaculada; Leyva Perez, Antonio (Royal Society of Chemistry, 2022-12-06)

[EN] Ligand-free sub-nanometer metal clusters (MCs) of Pt, Ir, Rh, Au and Cu, are prepared here in neat water and used as extremely active (nM) antitumoral agents for HeLa and A2870 cells. The preparation just consists of ...
MOF-Stabilized Perfluorinated Palladium Cages Catalyze the Additive-Free Aerobic Oxidation of Aliphatic Alcohols to Acids

Greco, Rossella; Tiburcio-Fortes, Estefania; Fernandez, Antonio; Marini, Carlo; Vidal Moya, José Alejandro; Oliver-Meseguer, Judit; Armentano, Donatella; Pardo, Emilio; Ferrando-Soria, Jesus; Leyva Perez, Antonio (John Wiley & Sons, 2022-01)

[EN] Extremely high electrophilic metal complexes, composed by a metal cation and very electron poor sigma-donor ancillary ligands, are expected to be privileged catalysts for oxidation reactions in organic chemistry. ...
Parts-per-million of ruthenium catalyze the selective chain-walking reaction of terminal alkenes

Sanz-Navarro, Sergio; Mon-Conejero, Marta; Doménech-Carbó, Antonio; Greco, Rossella; Sánchez-Quesada, Jorge; Espinós-Ferri, Estela; Leyva Perez, Antonio (Nature Publishing Group, 2022-05-20)

[EN] The chain-walking of terminal alkenes (also called migration or isomerization reaction) is currently carried out in industry with unselective and relatively costly processes, to give mixtures of alkenes with significant ...
Regioirregular and catalytic Mizoroki-Heck reactions

Garnes-Portoles, Francisco; Greco, Rossella; Oliver-Meseguer, Judit; Castellanos-Soriano, Jorge; Jiménez Molero, María Consuelo; Lopez-Haro, Miguel; Hernández-Garrido, Juan Carlos; Boronat Zaragoza, Mercedes; Pérez-Ruiz, Raúl; Leyva Perez, Antonio (Nature Publishing Group, 2021-04)

[EN] The palladium-catalysed cross-coupling reaction between alkenes and aryl halides (the Mizoroki-Heck reaction) is a powerful methodology to construct new carbon-carbon bonds. However, the success of this reaction is ...
Self-Assembly of Catalytically Active Supramolecular Coordination Compounds within Metal Organic Frameworks

Adam-Ortiz, Rosa; Mon, M.; Greco, Rossella; Kalinke, Lucas H.G.; Vidal Moya, José Alejandro; Fernandez, Antonio; Winpenny, Richard E.P.; Doménech-Carbó, Antonio; Leyva Perez, Antonio; Armetano, Donatella; Pardo, Emilio; Ferrando-Soria, Jesús (American Chemical Society, 2019-07-03)

[EN] Supramolecular coordination compounds (SCCs) represent the power of coordination chemistry methodologies to self-assemble discrete architectures with targeted properties. SCCs are generally synthesized in solution, ...
Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids

Tiburcio, Estefanía; Greco, Rossella; Mon-Conejero, Marta; Ballesteros-Soberanas, Jordi; Ferrando-Soria, Jesus; Lopez-Haro, Miguel; Hernández-Garrido, Juan Carlos; Oliver-Meseguer, Judit; Marini, Carlo; Boronat Zaragoza, Mercedes; Armentano, Donatella; Leyva Perez, Antonio; Pardo, Emilio (American Chemical Society, 2021-02-04)

[EN] Metal single-atom catalysts (SACs) promise great rewards in terms of metal atom efficiency. However, the requirement of particular conditions and supports for their synthesis, together with the need of solvents and ...