Dolle, Christian; Oestreicher, Víctor; Ruiz, Alberto M.; Kohring, Malte; Garnes-Portoles, Francisco; Wu, Mingjian; Sánchez-Santolino, Gabriel; Seijas-Da Silva, Alvaro; Alcaraz, Marta; Eggeler, Yolita M.; Spiecker, Erdmann; Canet-Ferrer, Josep; Leyva Perez, Antonio; Weber, Heiko B.; Varela, María(American Chemical Society, 2023-06-01)
[EN] High-quality devices based on layered heterostructuresare typicallybuilt from materials obtained by complex solid-state physical approachesor laborious mechanical exfoliation and transfer. Meanwhile, wet-chemicallysynthesized ...
Garnes-Portoles, Francisco; Leyva Perez, Antonio(American Chemical Society, 2023-07-03)
[EN] The synthesis ofmacrocycles is fundamental to obtainuseful quantitiesof this unique family of organic compounds. However, most currentsyntheses still require highly diluted conditions (generally <0.1M), which makes ...
[EN] The synthesis of cyclized organic compounds with more than ten atoms (macrocycles) is traditionally based on reversible reactions under highly diluted conditions, typically <0.05¿M, in order to circumvent the formation ...
Garnes-Portoles, Francisco; Rivero-Crespo, Miguel Ángel; Leyva Perez, Antonio(Elsevier, 2020-12)
[EN] The cyanosilylation of carbonyl compounds is a fundamental reaction in organic synthesis, to give cyanohydrins. Ketones are particularly reluctant to cyanosilane addition and require the action of a catalyst, and ...
Garnes Pórtoles, Francisco(Universitat Politècnica de València, 2023-07-17)
[ES] En la presente tesis doctoral se ha llevado a cabo un estudio de nuevas reacciones orgánicas de interés catalizadas por diferentes especies de paladio, tanto clústeres como complejos metálicos.
En primer lugar, se ...
[EN]
The industrially-viable aerobic alpha-alkylation of cyclic and acyclic ketones with allyl and alkyl alkenes in the presence of catalytic amounts of Mn2+, under homo- and heterogeneous conditions, is achieved here. ...
[EN] The palladium-catalysed cross-coupling reaction between alkenes and aryl halides (the Mizoroki-Heck reaction) is a powerful methodology to construct new carbon-carbon bonds. However, the success of this reaction is ...