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Listar por autor "Bilanin Artigado, Cristina"

Mostrando ítems 1-10 de 10

Acid and Base Water Coexists in a Micro-Structured Ionic Liquid and Catalyzes Organic Reactions in One-Pot

Leyva Perez, Antonio; Bilanin-Artigado, Cristina; Bacic, Matea; Greco, Rossella (John Wiley & Sons, 2022-10-10)

[EN] The most paradigmatic example of antagonist chemical species are protons and hydroxyls, and their coexistence in a liquid system is of high interest. Here we show that commercial ionic liquids stabilize microdroplets ...
Crystallographic Visualization of a Double Water Molecule Addition on a Pt-1-MOF during the Low-temperature Water-Gas Shift Reaction

Bilanin-Artigado, Cristina; Tiburcio, Estefanía; Ferrando-Soria, Jesús; Armentano, Donatella; Leyva Perez, Antonio; Pardo, Emilio (John Wiley & Sons, 2021-02-18)

[EN] The low-temperature water-gas shift reaction (WGSR, CO+H2O H-2+CO2) is considered a very promising reaction -candidate for fuel cells- despite an efficient and robust catalyst is still desirable. One of the more ...
Epoxidation vs. dehydrogenation of allylic alcohols: heterogenization of the VO(acac)(2) catalyst in a metal-organic framework

Negro, Cristina; Bilanin-Artigado, Cristina; Qu, Xiaoni; Oliver-Meseguer, Judit; Ferrando-Soria, Jesus; Leyva Perez, Antonio; Armentano, Donatella; Pardo, Emilio (The Royal Society of Chemistry, 2022-05-05)

[EN] Allylic alcohol epoxidation and dehydrogenation reactivity is distinguished when VO(acac)(2) is used in solution or anchored in a metal-organic framework (MOF). The chemical mechanism depends on the electronic profile ...
Functionalization of polyethylene with hydrolytically-stable ester groups

Hervàs-Arnandis, Susi; Palomar-De Lucas, Brenda; Bilanin-Artigado, Cristina; Mingueza-Verdejo, Paloma; Viciano, Mónica; Oliver-Meseguer, Judit; Leyva Perez, Antonio (The Royal Society of Chemistry, 2023-08-04)

[EN] Low-density (LD) and high-density polyethylene (HDPE), recycled or not, incorporates up to 7 wt% of ester groups after reacting either with ethyl diazoacetate (EDA) under catalytic and solvent free-reaction conditions, ...
Metaloporfirinas: Síntesis, actividad catalítica y soporte en materiales 2D

Bilanin Artigado, Cristina (Universitat Politècnica de València, 2020-10-16)

[ES] Las metaloporfirinas son un tipo de complejos organometálicos que presentan gran relevancia en la química de la vida y que han despertado un gran interés en los últimos años en el campo de la catálisis. En este ...
MOF-Triggered Synthesis of Subnanometer Ag02 Clusters and Fe3+ Single Atoms: Heterogenization Led to Efficient and Synergetic One- Pot Catalytic Reactions

Tiburcio, Estefanía; Zheng, Yongkun; Bilanin-Artigado, Cristina; Hernández-Garrido, Juan Carlos; Vidal Moya, José Alejandro; Oliver-Meseguer, Judit; Martín-García, Nuria; Mon-Conejero, Marta; Ferrando-Soria, Jesus; Armentano, Donatella; Leyva Perez, Antonio; Pardo, Emilio (American Chemical Society, 2023-05-10)

[EN] The combination of well-defined Fe3+ isolated single-metal atoms and Ag2 subnanometer metal clusters within the channels of a metal¿organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction ...
One-Pot Synthesis of Terminal Alkynes from Alkenes

Bilanin-Artigado, Cristina; Singh, Amravati Shivaji; Martínez-Belenguer, Lluis; Leyva Perez, Antonio (American Chemical Society, 2024-08-05)

[EN] The direct synthesis of terminal alkynes from widely available terminal alkenes is an unmet challenge in organic synthesis. Here, we show that alkyl and aromatic terminal alkenes can be converted to the corresponding ...
Parametrization of Catalytic Organic Reactions with Convex Hammett Plots

Leyva Perez, Antonio; Ballesteros-Soberanas, Jordi; Bilanin-Artigado, Cristina (American Chemical Society, 2023-02-01)

[EN] Quantification is essential to fairly compare between synthetic reactions in chemistry. Here we propose two new parameters called "adapted sensitivity constant" (rho(adap)) and "substrate electronics adaptability" ...
Selective cycloaddition of ethylene oxide to CO2 within the confined space of an amino acid-based metal-organic framework

Bilanin-Artigado, Cristina; Escamilla, Paula; Ferrando-Soria, Jesus; Leyva Perez, Antonio; Armentano, Donatella; Pardo, Emilio (The Royal Society of Chemistry, 2023-11-13)

[EN] Host-guest chemistry within the confined space of metal-organic frameworks (MOFs) offers an almost unlimited myriad of possibilities, hardly accessible with other materials. Here we report the synthesis and physical ...
Síntesis directa de alquinos a partir de alquenos con distintos catalizadores metálicos

Bilanin Artigado, Cristina (Universitat Politècnica de València, 2024-07-11)

[ES] En la presente tesis doctoral se estudian dos nuevas rutas sintéticas diseñadas para obtener alquinos directamente a partir de alquenos, utilizando diferentes catalizadores metálicos. Dichos catalizadores han ayudado ...