Leyva Perez, Antonio; Rubio Marqués, Paula; AL-Dejab, Salem S.; Al-Resayes, Saud I.; Corma Canós, Avelino(American Chemical Society, 2011)
[EN] Orthogonal sigma,pi-bisfunctionalization of terminal alkynes can be achieved with a cationic gold complex in catalytic amounts. First, the terminal C-H bond is transformed to the corresponding bromoalkyne which is ...
Electrochemical monitoring of the oxidative coupling of alkynes in the homogeneous phase through catalytic cycles involving triphenylphosphine gold complexes and selectfluor as oxidant reveals that at least two gold species ...
Oliver Meseguer, Judit; Leyva Perez, Antonio; Al-Resayes, Saud I.; Corma Canós, Avelino(Royal Society of Chemistry, 2013-09-14)
Gold complexes and salts decompose to catalytically active 3¿5 atom gold clusters during the one-pot acylation¿hydration of propargyl alcohols. Kinetic and spectroscopic studies show that released ligands and counteranions ...
Leyva Perez, Antonio; Doménech, Antonio; Al-Resayes, Saud I.; Corma Canós, Avelino(American Chemical Society, 2011-12)
[EN] Au(I)/Au(III) catalytic cycles are catalytically competent to perform the oxidative coupling of alkynes in the homogeneous phase at room temperature and without any protecting atmosphere. Selectfluor as oxidant, wet ...
Leyva Perez, Antonio; Oliver Meseguer, Judit; Cabrero Antonino, Jose Ramón; Rubio Marqués, Paula; Serna, Pedro; Al-Resayes, Saud I.; Corma Canós, Avelino(American Chemical Society, 2013-07)
[EN] Propiolates cyclotrimerize in the presence of catalytic amounts of gold nanoparticles to give aryl benzoates in high yields and with turnover frequencies of thousands per hour. Types of alkynes other than propiolates ...
Cabrero Antonino, Jose Ramón; García Fernández, María Teresa; Rubio Marqués, Paula; Vidal Moya, José Alejandro; Leyva Perez, Antonio; Al-Deyab, Salem S.; Al-Resayes, Saud I.; Díaz Morales, Urbano Manuel; Corma Canós, Avelino(American Chemical Society, 2011)
[EN] Two di¿erent diamines, namely, Tr¿oger base and
dimethylethylene diamine (DMEDA) functionalized with disilane groups, have been condensed with silica precursors to form
mesoporous hybrid organic-inorganic materials. ...
Leyva Perez, Antonio; Cabrero Antonino, Jose Ramón; Rubio Marqués, Paula; Al-Resayes, Saud I.; Corma Canós, Avelino(American Chemical Society, 2014-03)
Aryl ketones substituted in ortho, meta, and
para position are prepared by a palladium-catalyzed Sonogashira
reaction followed by a regioselective hydration of the soformed
alkyne with triflimidic acid or a gold catalyst, ...