[EN] Ultrasmall silver clusters in reduced state are difficult to synthesize since silver atoms tend to rapidly aggregate into bigger entities. Here, we show that dimers of reduced silver (Ag-2) are formed within the ...
Zheng, Yongkun(Universitat Politècnica de València, 2024-09-02)
[ES] Los carbenos representan una clase de reactivos altamente potentes utilizados en el campo de la síntesis orgánica, que muestran la capacidad de participar eficazmente durante los procesos de inserción en una amplia ...
[EN] The preparation of novel efficient catalyststhat could be applicable in industrially important chemical processeshas attracted great interest. Small subnanometer metal clusters can exhibit outstanding catalytic ...
[EN] The selective ortho-alkylation of 1-naphthol with methanol is carried out over various commercially available acid solid catalysts under relatively mild reaction conditions (<300 degrees C), in batch, and anhydrous ...
[EN] The combination of well-defined Fe3+ isolated single-metal atoms and Ag2 subnanometer metal clusters within the channels of a metal¿organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction ...
Zheng, Yongkun; Vidal Moya, José Alejandro; Hernández-Garrido, Juan Carlos; Mon-Conejero, Marta; Leyva Perez, Antonio(American Chemical Society, 2023-11-03)
[EN] Commercially available zeolite Y modulates the catalytic activity and selectivity of ultrasmall silver species during the Buchner reaction and the carbene addition to methylene and hydroxyl bonds, by simply exchanging ...