Rubio Marqués, Paula; Hernández Garrido, Juan Carlos; Leyva Perez, Antonio; Corma Canós, Avelino(Royal Society of Chemistry, 2014)
Cyclohexanone oxime is formed from nitrobenzene with 97% yield
in a one-pot reaction catalysed by palladium and gold nanoparticles
on carbon. The reaction is carried out under hydrogen at
60 8C and the overall transformation ...
[EN] The palladium-catalysed cross-coupling reaction between alkenes and aryl halides (the Mizoroki-Heck reaction) is a powerful methodology to construct new carbon-carbon bonds. However, the success of this reaction is ...
Ballesteros-Soberanas, Jordi; Hernández-Garrido, Juan Carlos; Cerón-Carrasco, José Pedro; Leyva Perez, Antonio(Elsevier, 2022-04)
[EN] The de-novo synthesis of soluble or solid-supported Pd-(CaCO3)(n) clusters (n = 2-13) and their high catalytic activity for the semi-hydrogenation of internal alkynes compared to terminal alkynes, is presented. ...
[EN] Metal single-atom catalysts (SACs) promise great rewards in terms of metal atom efficiency. However, the requirement of particular conditions and supports for their synthesis, together with the need of solvents and ...