Sheikhi, Ehsan; Rezaei, Narjes; Castilla, Alvaro; Sanz-Marco, Amparo; Vila, Carlos; Muñoz Roca, María Del Carmen; Pedro, Jose R.; Blay, Gonzalo(John Wiley & Sons, 2021-10-07)
[EN] An enantioselective organocatalytic addition of sodium bisulfite to (E)-nitroalkenes has been developed by using a chiral bifunctional organocatalyst. The present methodology provides a variety of chiral beta-nitroe ...
Blay, Gonzalo; Muñoz Roca, María del Carmen; Pedro, Jose R; Sanz-Marco, Amparo(Wiley-VCH Verlag, 2013-04-15)
A new enantioselective catalyst for the
conjugate addition of terminal alkynes has been developed.
Terminal alkynes react with 3-alkoxycarbonylcoumarins
in the presence of diethylzinc and
bis(hydroxyamide) ligands to ...
Sanz-Marco, Amparo; Blay, Gonzalo; Muñoz Roca, María Del Carmen; Pedro, J.R.(Royal Society of Chemistry, 2015)
[EN] The conjugate diynylation of a,b-unsaturated trifluoromethyl ketones is
carried out in the presence of a low catalytic load (2.5 mol%) of a
copper(I)–MeOBIPHEP complex, triethylamine and a terminal 1,3-diyne.
Pre ...