[EN] Amides and esters are prevalent chemicals in Nature, industry and academic laboratories. Thus, it is not surprising that a plethora of synthetic methods for these compounds has been developed along the years. However, ...
Rivero-Crespo, Miguel Ángel; Mon, Marta; Ferrando-Soria, Jesus; Lopes, Christian W.; Boronat Zaragoza, Mercedes; Leyva Perez, Antonio; Corma Canós, Avelino; Hernandez-Garrido, Juan carlos; López-Haro, Miguel; Calvino, Jose J.; Ramos-Fernandez, Enrique V.; Armentano, Donatella; Pardo, Emilio(John Wiley & Sons, 2018-12-21)
[EN] The synthesis and reactivity of single metal atoms in a low-valence state bound to just water, rather than to organic ligands or surfaces, is a major experimental challenge. Herein, we show a gram-scale wet synthesis ...
[EN] The low-temperature water-gas shift reaction (WGSR, CO+H2O H-2+CO2) is considered a very promising reaction -candidate for fuel cells- despite an efficient and robust catalyst is still desirable. One of the more ...
Negro, Cristina; Bilanin-Artigado, Cristina; Qu, Xiaoni; Oliver-Meseguer, Judit; Ferrando-Soria, Jesus; Leyva Perez, Antonio; Armentano, Donatella; Pardo, Emilio(The Royal Society of Chemistry, 2022-05-05)
[EN] Allylic alcohol epoxidation and dehydrogenation reactivity is distinguished when VO(acac)(2) is used in solution or anchored in a metal-organic framework (MOF). The chemical mechanism depends on the electronic profile ...
[EN] The preparation of novel efficient catalyststhat could be applicable in industrially important chemical processeshas attracted great interest. Small subnanometer metal clusters can exhibit outstanding catalytic ...
[EN] The exact chemical structure of non-crystallising natural products is still one of the main challenges in Natural Sciences. Despite tremendous advances in total synthesis, the absolute structural determination of a ...
[EN] The search for simple, earth-abundant, cheap, and nontoxic metal catalysts able to perform industrial hydrogenations is a topic of interest, transversal to many catalytic processes. Here, we show that isolated FeIII¿O ...
[EN] The synthesis of mixed-component metal-organic frameworks (MOFs) -including multivariate MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and metals MOFs- is becoming a very active research ...
Adam-Ortiz, Rosa; Mon, M.; Greco, Rossella; Kalinke, Lucas H.G.; Vidal Moya, José Alejandro; Fernandez, Antonio; Winpenny, Richard E.P.; Doménech-Carbó, Antonio; Leyva Perez, Antonio; Armetano, Donatella; Pardo, Emilio; Ferrando-Soria, Jesús(American Chemical Society, 2019-07-03)
[EN] Supramolecular coordination compounds (SCCs) represent the power of coordination chemistry methodologies to self-assemble discrete architectures with targeted properties. SCCs are generally synthesized in solution, ...
[EN] Metal single-atom catalysts (SACs) promise great rewards in terms of metal atom efficiency. However, the requirement of particular conditions and supports for their synthesis, together with the need of solvents and ...
[EN] Imines are ubiquitous intermediates in organic synthesis, and the metal-mediated imination of alcohols is one of the most direct and simple methods for their synthesis. However, reported protocols lack compatibility ...
Juan Alcañiz, Jana; Ferrando-Soria, Jesus; Luz Mínguez, Ignacio; Serra-Crespo, Pablo; Skupien, Emmanuel; Santos, Vera P.; Pardo, Emilio; Llabrés i Xamena, Francesc Xavier; Kapteijn, Freek; Gascon, Jorge(Elsevier, 2013-11)
A new consecutive post-functionalization method has been developed for the inclusion of additional metal functionalities in Metal Organic Frameworks (MOFs) through oxamate as chelating agent. This may result in catalytic ...