[EN] Molecular molybdenum cluster sulphides are an unexpensive alternative to noble
metal based homogenous catalysts. In this paper, we present the synthesis of the first PNP Mo3S4
derivative as well as the crystal structure ...
[EN] A new molybdenum siloxo cluster of formula [Mo3S4(dmpe)(3)(MPTES)(3)]PF6 (dmpe = 1,2-(bis)dimethylphosphinoethane; MPTES = (3-mercaptopropyl)triethoxysilane) has been synthesized with the ultimate goal of incorporating ...
Beltran, Tomas F.; Feliz Rodriguez, Marta; Llusar, Rosa; Mata, Jose A.; Safont, Vicent S.(American Chemical Society, 2011)
[EN] The catalytic hydrodefluorination (HDF) of pentafluoropyridine in the presence of arylsilanes is catalyzed by the tungsten and molybdenum(IV) cluster hydrides of formula [M3
S4 H3(dmpe)3] ¿, W-1¿for M = W and Mo-1¿for ...
Molybdenum(IV) hydroxo [Mo3S4(dmpe)3(OH)3]+ (1+) and hydrosulfido [Mo3S4(dmpe)3(SH)3]+ (2+) [dmpe = 1,2-bis(dimethylphosphanyl)ethane] trimetallic cuboidal cluster complexes have been isolated in high yields by treating ...