Schwalbe-Koda, Daniel; Kwon, Soonhyoung; Paris, Cecilia; Bello-Jurado, Estefanía; Jensen, Zach; Olivetti, Elsa; Willhammar, Tom; Corma Canós, Avelino; Román-Leshkov, Yuriy; Moliner Marin, Manuel; Gomez-Bombarelli, Rafael(American Association for the Advancement of Science (AAAS), 2021-10-15)
[EN] Zeolites are versatile catalysts and molecular sieves with large topological diversity, but managing phase competition in zeolite synthesis is an empirical, labor-intensive task. In this work, we controlled phase ...
[EN] Approaching the level of molecular recognition of enzymes with solid catalysts is a challenging goal, achieved in this work for the competing transalkylation and disproportionation of diethylbenzene catalyzed by acid ...
[EN] Zeolites are inorganic materials with wide industrial applications due to their topological diversity. Tailoring confinement effects in zeolite pores, for instance by crystallizing intergrown frameworks, can improve ...
[EN] Cu-exchanged zeolites rely on mobile solvated Cu+ cations for their catalytic activity, but the role of the framework composition in transport is not fully understood. Ab initio molecular dynamics simulations can ...
[EN] We report the one-pot synthesis of a chabazite (CHA)/erionite (ERI)-type zeolite intergrowth structure characterized by adjustable extents of intergrowth enrichment and Si/Al molar ratios. This method utilizes readily ...
[EN] Zeolites span a large variety of microporous crystal structures, making them useful materials for catalysis and separations. However, controlling phase competition in their synthesis often requires organic structure-directing ...