Seredyuk, Maksym; Znovjyak, Kateryna; Valverde-Muñoz, Francisco Javier; da Silva, Ivan; Muñoz Roca, María Del Carmen; Moroz, Yurii S.; Real, José Antonio(American Chemical Society, 2022-08-10)
[EN] Little is known about the mechanisms behind the bistability (memory) of molecular spin transition compounds over broad temperature ranges (>100 K). To address this point, we report on a new discrete Fe-II neutral ...
Seredyuk, Maksym; Znovjyak, Kateryna; Valverde-Muñoz, Francisco Javier; Muñoz Roca, María Del Carmen; Fritsky, Igor O.; Amirkhanov, Volodymyr; Real, Jose A.(The Royal Society of Chemistry, 2022-02-01)
[EN] The structurally simple complex {Fe-II[tren(6F-py)(3)]}(BF4)(2) [tren(6F-py)(3) = tris(3-aza-4-(6-fluoro-2-pyridyl)-3-butenyl)amine] undergoes an abrupt spin transition (ST) with the critical temperature T down ...
Valverde Muñoz, Francisco Javier; Seredyuk, Maksym; Muñoz Roca, María del Carmen; Znovjyak, Kateryna; Fritsky, Igor O.; Real, José Antonio(American Chemical Society, 2016-10-17)
Self-assembling iron(II), 2-fluoropyrazine (Fpz),
and [MII(CN)4]
2− (MII = Ni, Pd, Pt) or [AuI
(CN)2]
− building
blocks have afforded a new series of two- (2D) and threedimensional
(3D) Hofmann-like spin crossover ...