[EN] A bifunctional metal organic framework catalyst containing palladium and copper(II) benzene- 1,3,5-tricarboxylate - MOF-Cu(BTC)-[Pd] - has been prepared. This catalyst enables the performance of the tandem Sonogashira/click ...
Rasero-Almansa, A. M; Corma Canós, Avelino; Iglesias, M.; Sánchez Alonso, Felix(Wiley-VCH Verlag, 2014-06)
[EN] The direct N-alkylation of amines with alcohols was performed with an Ir-Zr-based metal-organic framework multifunctional heterogeneous catalyst. This system is efficient and environmentally benign for the synthesis ...
Merino Marcos, Estibaliz; Verde Sesto, Ester; Maya, Eva M.; Corma Canós, Avelino; Iglesias, Marta; Sánchez Alonso, Felix(Elsevier, 2014-01-17)
[EN] Porous aromatic frameworks (PPAFs) prepared by microwave assisted synthesis can be easily func-tionalized to obtain solid acid (sulfonic acid) and base (primary amine) catalysts. This porous materialdemonstrated to ...
[EN] Supported ruthenium complexes based on electron-rich (NHC)NN-pincer-type ligands selectively catalyze the formation of substituted amines from nitroaromatics and carbonyl compounds through a series of consecutive steps ...
We describe the postsynthetic modification of Zr-based metal organic frameworks (MOFs) containing chiral NNN-pincer ligands based on aminopyridineimines, as well as the subsequent formation of (NNN)-M-Zr-MOF complexes ...
Rasero Almansa, Antonia Maria; Corma Canós, Avelino; Iglesias, Marta; Sánchez Alonso, Felix(Royal Society of Chemistry, 2014)
[EN] The multifunctional heterogeneous catalyst iridium–Zr-based MOF is able to effectively catalyze the hydrogenation of aromatic compounds in high yields under mild conditions. The catalyst was found to be highly active ...