Rivero-Crespo, Miguel Ángel; Mon, Marta; Ferrando-Soria, Jesus; Lopes, Christian W.; Boronat Zaragoza, Mercedes; Leyva Perez, Antonio; Corma Canós, Avelino; Hernandez-Garrido, Juan carlos; López-Haro, Miguel; Calvino, Jose J.; Ramos-Fernandez, Enrique V.; Armentano, Donatella; Pardo, Emilio(John Wiley & Sons, 2018-12-21)
[EN] The synthesis and reactivity of single metal atoms in a low-valence state bound to just water, rather than to organic ligands or surfaces, is a major experimental challenge. Herein, we show a gram-scale wet synthesis ...
Greco, Rossella; García-Laínez, Guillermo; Oliver-Meseguer, Judit; Marini, Carlo; Domínguez, Irene; Lopez-Haro, Miguel; Hernandez-Garrido, Juan Carlos; Cerón-Carrasco, José Pedro; Andreu, Inmaculada; Leyva Perez, Antonio(Royal Society of Chemistry, 2022-12-06)
[EN] Ligand-free sub-nanometer metal clusters (MCs) of Pt, Ir, Rh, Au and Cu, are prepared here in neat water and used as extremely active (nM) antitumoral agents for HeLa and A2870 cells. The preparation just consists of ...