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Catalytic Enantioselective Aza-Reformatsky Reaction with Cyclic Imines

De Munck, Lode; Vila, Carlos; Muñoz Roca, María del Carmen; Pedro, José R. (Wiley, 2016-12-05)

A catalytic highly enantioselective aza-Reformatsky reaction with cyclic aldimines and ketimines for the synthesis of chiral b-amino esters with good yields and excellent enantioselectivities is reported.Areadily ...
Catalytic enantioselective aza-Reformatsky reaction with seven-membered cyclic imines dibenzo[b,f][1,4]oxazepines

De Munck, Lode; Sukowski, Verena; Vila, Carlos; Muñoz Roca, María Del Carmen; Pedro, José R. (Royal Society of Chemistry, 2017-08-01)

[EN] A catalytic enantioselective aza-Reformatsky reaction is reported with cyclic dibenzo[b,f][1,4]oxazepines and ethyl iodoacetate leading to the synthesis of chiral ethyl 2-(10,11-dihydrodibenzo[b,f][1,4]oxazepin-11- ...
Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates

De Munck, Lode; Monleón, A.; Vila, C.; Muñoz Roca, María Del Carmen; Pedro, J. R. (The Royal Society of Chemistry, 2015-06)

[EN] (R)-VAPOL-Zn(II) complexes catalysed the enantioselective addition of terminal alkynes to cyclic benzoxathiazine 2,2-dioxides, providing the corresponding chiral propargylic sulfamidates with high yields (up to 93%) ...

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