The electronic structures and band gaps of MFU-4-type metal-organic frameworks can be systematically engineered leading to a family of isostructural microporous solids. Electrical properties of the microcrystalline samples ...
Liu, Ying-Ya; Grzywa, Maciej; Tonigold, Markus; Sastre Navarro, German Ignacio; Schuettrigkeit, Tanja; Leeson, Nicholas S.; Volkmer, Dirk(Royal Society of Chemistry, 2011)
The syntheses of Kuratowski-type pentanuclear clusters featuring {MZn4Cl4} cores (M-II = Ru or Zn) that incorporate triazolate ligands are described. The coordination compounds are characterized by single-crystal X-ray ...
Sastre Navarro, German Ignacio; van den Bergh, Johan; Kapteijn, Freek; Denysenko, Dmytro; Volkmer, Dirk(Royal Society of Chemistry, 2014)
The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small ...