Liu, Lichen; MEIRA, DEBORA M.; Arenal, Raul; Concepción Heydorn, Patricia; Puga, Alberto V.; Corma Canós, Avelino(American Chemical Society, 2019-12-06)
[EN] Identification of active sites in heterogeneous metal catalysts is critical for understanding the reaction mechanism at the molecular level and for designing more efficient catalysts. Because of their structural ...
Liu, Lichen; Arenal, Raul; Meira, Debora M.; Corma Canós, Avelino(The Royal Society of Chemistry, 2019-02-07)
[EN] In this work, we will report the generation of Au clusters in a purely siliceous MCM-22 zeolite. The catalytic properties of these Au clusters have been tested for the selective oxidation of cyclohexane to cyclohexanol ...
[EN] Single metal atoms and metal clusters have attracted much attention thanks to their advantageous capabilities as heterogeneous catalysts. However, the generation of stable single atoms and clusters on a solid support ...
[EN] The catalytic subnanometric metal clusters with a few atoms can be regarded as an intermediate state between single atoms and metal nanoparticles (>1 nm). Their molecule-like electronic structures and flexible geometric ...
[EN] Realizing the full potential of oxide-supported single-atom metal catalysts (SACs) is key to successfully bridge the gap between the fields of homogeneous and heterogeneous catalysis. Here we show that the one-pot ...