Rubio Marqués, Paula; Leyva Perez, Antonio; Corma Canós, Avelino(Royal Society of Chemistry, 2013)
[EN] Nitroderivatives are transformed to cyclohexylanilines at room temperature in good yields and selectivity via a hydrogenation-amine coupling cascade reaction using Pd nanoparticles on carbon as a catalyst and a Bronsted acid.
Taketoshi, Ayako; Concepción Heydorn, Patricia; García Gómez, Hermenegildo; Corma Canós, Avelino; Haruta, Masatake(Chemical Society of Japan, 2013-12-15)
Although selective oxidation of sulfides to sulfoxides with molecular oxygen is a difficult reaction due to the overoxidation to sulfone, manganese oxides were found to catalyze the aerobic oxidation of sulfides to sulfoxides ...
Dhaeyere, Frederic(Universitat Politècnica de València, 2021-09-01)
[ES] El desarrollo de nuevas metodologías sintéticas que permitan la preparación de compuestos de elevado valor añadido en la industria de un modo mucho más sostenible desde el punto de vista ambiental, con control de la ...
The selective acetalization of 5-hydroxymethylfurfural (HMF) with long chain alkyl alcohols has been performed to obtain precursor of molecules with surfactants properties. If direct acetalization of HMF with n-octanol is ...
[EN] Citrus fruits are characterized by a complex mixture of volatiles making up their characteristic aromas, being the D-limonene the most abundant one. However, its role on citrus fruit and juice odor is controversial. ...
Rivero-Crespo, Miguel A.; Rubio Marqués, Paula; Hernández-Garrido, Juan Carlos; Mon-Conejero, Marta; Oliver-Meseguer, Judit; Leyva Perez, Antonio(The Royal Society of Chemistry, 2023-04-24)
[EN] The use of bimetallic nanoparticles as catalysts in complex organic synthesis is rare, despite the widespread use of these materials in thermal C-1 chemistry and electrocatalysis. Here we show that intimate RuPt ...
[EN] Establishingtandem catalytic synthetic strategies basedon theuse of readily available, stable, and renewable feedstocks is of greatsignificant for the sustainable advancement of chemical-related industries.The key to ...
El Kadib, Abdelkrim; Primo Arnau, Ana María; Molvinger, Karine; Bousmina, Mosto; Brunel, Daniel(Wiley-VCH Verlag, 2011-07-04)
The ability of chitosan biopolymer to coordinate vanadium, tungsten and molybdenum metallic species and to control their mineralisation growth provides a new family of surface-reactive organic-inorganic hybrid microspheres. ...
[EN] Octahedral tantalum clusters are redox-active compounds. [{Ta6Bri12}Bra2(H2O)a4]·4H2O (i = inner; a = apical ligands) cluster results in efficient pre-catalyst for the light-driven H2 production from aqueous protons ...
Gallego Rodríguez, Mario(Universitat Politècnica de València, 2024-09-02)
[ES] Se investigó la reacción de metano a metanol (MTM) en zeolitas y zeotipos utilizando clústeres subnanométricos de cobre soportados usando como oxidante O2 y sin la intervención de moléculas de agua en todo momento.
Para ...
[EN] The partial oxidation of methane to methanol with molecular O2 at mild reaction conditions is a challenging process, which is efficiently catalyzed in nature by enzymes. As an alternative to the extensively studied ...
Primo Arnau, Ana María; Concepción Heydorn, Patricia; Corma Canós, Avelino(Royal Society of Chemistry, 2011)
Ruthenium nanoparticles supported on titania are over three times more active than conventional ruthenium on carbon for the hydrogenation of lactic acid. This superior catalytic activity can be due to a combined action of ...
[EN] Herein, a novel silver and chromium nanostructured N-doped carbonaceous material has been synthesized by a biomass-annealing approach using readily available chitosan as a raw material. The resulting catalyst AgCr@CN-800 ...