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A heterogeneous mechanism for the catalytic decomposition of hydroperoxides and oxidation of alkanes over CeO2 nanoparticles: A combined theoretical and experimental study

López Auséns, Javier Tirso; Boronat Zaragoza, Mercedes; Concepción Heydorn, Patricia; Chouzier, Sandra; Mastroianni, Sergio; Corma Canós, Avelino (Elsevier, 2016)

[EN] A nanoparticulate CeO2 catalyst is presented that is able to oxidize cyclohexane to K/A-oil (a mixture of cyclohexanone and cyclohexanol) using hydroperoxides as oxidizing species. The improvement in selectivity with ...
Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies

Bruijnincx Pieter C. A; Buurmans, Inge L. C; Huang, Yuxing; Juhász, Gergely; Viciano-Chumillas, Marta; Quesada Vilar, Manuel; Reedijk, Jan; Lutz, Martin; Spek, Anthony L.; Munck, Eckard; Bominaar, Emile L.; Klein Gebbink, Robertus J. M. (American Chemical Society, 2011-09-08)

[EN] The newly synthesized dinuclear complex [Fe-2(III)(mu-OH)(2)(bik)(4)](NO3)(4) (1) (bik, bis(1-methylimidazol-2-yl)ketone) shows rather short Fe center dot center dot center dot Fe (3.0723(6) angstrom) and Fe-O distances ...

Mostrando ítems 1-2 de 2