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Mostrando ítems 1-3 de 3

Cianosililación de cetonas catalizada por óxido de cerio. Estudio mecanístico

Rivero Crespo, Miguel Ángel (Universitat Politècnica de València, 2015-09-18)

[EN] Cyanosilylation of carbonylic compounds has a great interest in organic chemistry. In the present work ketones cyanosilylation is performed catalyzed by cerium oxide in mild conditions. A kinetic study was carried ...
Nanoceria as a recyclable catalyst/support for the cyanosilylation of ketones and alcohol oxidation in cascade

Garnes-Portoles, Francisco; Rivero-Crespo, Miguel Ángel; Leyva Perez, Antonio (Elsevier, 2020-12)

[EN] The cyanosilylation of carbonyl compounds is a fundamental reaction in organic synthesis, to give cyanohydrins. Ketones are particularly reluctant to cyanosilane addition and require the action of a catalyst, and ...
Remarkable Acceleration of Benzimidazole Synthesis and Cyanosilylation Reactions in a Supramolecular Solid Catalyst

Rojas-Buzo, Sergio; García-García, Pilar; Corma Canós, Avelino (John Wiley & Sons, 2017)

[EN] A solid metal organic catalyst with hydrophobic pockets and Lewis acid centers strongly accelerates the reaction rate for organic reactions. This is exemplified for the cyanosilylation of ketones and for the synthesis ...

Mostrando ítems 1-3 de 3