[EN] The generation of a carbocation with an acid depends not only on the acid strength but also on the ability of the counteranion to stabilize the positive charge left behind. Here we report that despite their relatively ...
Selby, Jonathan D.; Feliz Rodriguez, Marta; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip(American Chemical Society, 2011)
[EN] New mono- and bis-cyclopentadienyl terminal titanium hydrazido(2-) compounds were prepared by tert-butyl imide/N,N'-disubstituted hydrazine exchange reactions. Reaction of Cp*Ti(N(t)Bu)Cl(PY) (1) with Ph(2)NNH(2) gave ...