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Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

Oliver Meseguer, Judit; Liu, Lichen; García García, Saray; Canós Giménez, Clàudia; Domínguez Pérez, Irene; GAVARA CLEMENTE, RAFAEL; Domenech Carbo, Antonio; Concepción Heydorn, Patricia; Leyva Perez, Antonio; Corma Canós, Avelino (American Chemical Society, 2015-03-25)

[EN] Sub-nanometric Cu clusters formed by endogenous reduction of Cu salts and Cu nanoparticles are active and selective catalysts for C−N, C−C, C−O, C−S, and C−P bond-forming reactions. Sub-nanometric Cu clusters ...
Trends in the Reactivity of Molecular O-2 with Copper Clusters: Influence of Size and Shape

Fernandez, Estefania; Boronat Zaragoza, Mercedes; Corma Canós, Avelino (American Chemical Society, 2015-08-27)

The adsorption and dissociation of molecular O-2 on copper clusters of varying size and morphology (Cur with n = 3-8, 13, and 38 atoms) has been systematically investigated using several DFT approaches. Different modes of ...

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