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'From the mole to the molecule': ruthenium catalyzed nitroarene reduction studied with 'bench', high-throughput and single molecule fluorescence techniques

Carrillo, Adela I.; Stamplecoskie, Kevin G.; Marín García, Mª Luisa; Scaiano, Juan C. (Royal Society of Chemistry, 2014)

Single molecule fluorescence microscopy techniques are used to complement conventional catalysis and high-throughput experiments in order to gain a complete picture of a model reaction. In these experiments a model nitroarene ...
From MOFs to zeolites: zirconium for epoxide rearrangement

Corma Canós, Avelino; Orozco Arboleda, Lina Marcela; Renz, Michael (Royal Society of Chemistry, 2013)

[EN] Zirconium Lewis acid sites grafted onto a mesoporous silicate (MCM-41) and zirconium sites incorporated into inorganic-organic MOF materials are employed successfully in the rearrangement of beta-pinene epoxide into ...
Making C-C bond with gold catalysts: A theoretical study of the influence of gold particle size on the dissociation of the C-X bond in aryl halides

Boronat Zaragoza, Mercedes; López Auséns, Javier Tirso; Corma Canós, Avelino (American Chemical Society, 2014-05-01)

The adsorption and activation of iodo-, bromo-, and chlorobenzene over gold catalysts of different size, including an extended Au(111) surface; three-dimensional Au38 and Au13 nanoparticles; and planar Au7, Au6, and Au3 ...
Well-Defined Noble Metal Single Sites in Zeolites as an Alternative to Catalysis by Insoluble Metal Salts

Rubio Marqués, Paula; Rivero Crespo, Miguel Ángel; Leyva Perez, Antonio; Corma Canós, Avelino (American Chemical Society, 2015-09-16)

Insoluble precious metal chlorides in polymeric form (i.e., PtCl2, PdCl2, AuCl, RhCl3) are commonly used as catalysts for a plethora of organic reactions in solution. Here we show that only the minor soluble fraction of ...

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