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A Ligand-Free Pt3 Cluster Catalyzes the Markovnikov Hydrosilylation of Alkynes with up to 106 Turnover Frequencies

Rivero-Crespo, Miguel Ángel; Leyva Perez, Antonio; Corma Canós, Avelino (John Wiley & Sons, 2017)

[EN] The Pt-catalyzed hydrosilylation of alkynes is the procedure of choice to obtain vinylsilanes, and is claimed to be the most relevant application of Pt in organic synthesis. More than half a century after its discovery, ...
Cobalt Catalysts for Alkene Hydrosilylation under Aerobic Conditions without Dry Solvents or Additives

Gutiérrez-Tarriño, Silvia; Concepción Heydorn, Patricia; Oña-Burgos, Pascual (John Wiley & Sons, 2018-12-06)

[EN] Alkene hydrosilylation is typically performed with Pt catalysts, but inexpensive base-metal catalysts would be preferred. Here, we report a simple method for the use of air-stable cobalt catalysts for anti-Markovnikov ...
Desarrollo de catalizadores de cobalto polinucleares y multifuncionales para la activación de moléculas pequeñas

Gutiérrez Tarriño, Silvia (Universitat Politècnica de València, 2021-09-02)

[ES] La presente tesis doctoral se enmarca en el ámbito de la Química Sostenible, en el cual se identifica la catálisis como una de las herramientas más importantes para su aplicación. En este sentido, en esta tesis doctoral, ...

Mostrando ítems 1-3 de 3