Real, J. A.; Gaspar, A. B.; Niel, V.; Muñoz Roca, María Del Carmen(Elsevier, 2003-01)
[EN] In the present article we discuss the cooperative nature of the spin crossover phenomenon in iron(II) complexes, providing a perspective of the state of the art in this area. The first aspect we discuss is the role ...
Gaspar, A. B.; Muñoz Roca, María Del Carmen; Moliner, N.; Ksenofontov, V.; Levchenko, G.; Gütlich, P.; Real, J. A.(Springer-Verlag, 2003-02)
[EN] The monomeric compounds [Fe(abpt)(2)(NCX)(2)] (X = S (1), Se (2) and abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) have been synthesized and characterized. They crystallize in the monoclinic P2(1)/n space group ...
Seredyuk, M.; Li, Ruixin; Znovjyak, Kateryna; Zhang, Zhe; Valverde-Muñoz, FJ; Valverde-Muñoz, Francisco Javier; Li, Bing; Muñoz Roca, María Del Carmen; Li, Quanjin; Liu, Bingbing; Levchenko, Georgiy; Real, J. A.(John Wiley & Sons, 2024-07)
[EN] Barocaloric cooling, that is, lowering the temperature of a material under pressure action, is an attractive solid-state effect that can potentially compete with volatile gas-based cooling. To observe the barocaloric ...
Ortega-Villar, Norma; Muñoz Roca, María del Carmen; Real, José A.(MDPI, 2016-03)
[EN] This review provides an up to date survey of a singular class of iron(II) spin crossover (SCO)
molecular materials that undergo high-spin (HS) Ø low-spin (LS) phase transitions accompanied
by crystallographic symmetry ...