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Conversion of Levulinic acid into chemicals: Synthesis of biomass derived levulinate esters over Zr-containing MOFs

García Cirujano, Francisco; Corma Canós, Avelino; Llabrés i Xamena, Francesc Xavier (Elsevier, 2015-03-03)

Zr-containing metal-organic frameworks (MOFs) formed by either terephthalate (UiO-66) or 2-aminoterephthalate ligancls (UiO-66-NH2) are active and stable catalysts for the acid catalyzed esterification of levulinic acid ...
Defect-Engineered Ruthenium MOFs as Versatile Heterogeneous Hydrogenation Catalysts

Epp, Konstantin; Luz, Ignacio; Heinz, Werner R.; Rapeyko, Anastasia; Llabrés i Xamena, Francesc Xavier; Fischer, Roland A. (John Wiley & Sons, 2020-03-19)

[EN] Ruthenium MOF [Ru-3(BTC)(2)Y-y] . G(g) (BTC=benzene-1,3,5-tricarboxylate; Y=counter ions=Cl-, OH-, OAc-; G=guest molecules=HOAc, H2O) is modified via a mixed-linker approach, using mixtures of BTC and pyridine-3,5-d ...
Selective Aerobic Oxidation of Cumene to Cumene Hydroperoxide over Mono- and Bimetallic Trimesate Metal Organic Frameworks Prepared by a Facile Green Aqueous Synthesis

Nowacka, Anna Elzbieta; Briantais, P.; PRESTIPINO, CARMELO; Llabrés i Xamena, Francesc Xavier (American Chemical Society, 2019-04-15)

[EN] Co-Ni and Mn-Ni bimetallic trimesate MOFs prepared by a fast aqueous synthesis method are excellent and reusable catalysts for the selective aerobic oxidation of cumene to cumene hydroperoxide (CHP). Isolation of Co2+ ...

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