Ballesteros-Soberanas, Jordi; Hernández-Garrido, Juan Carlos; Cerón-Carrasco, José Pedro; Leyva Perez, Antonio(Elsevier, 2022-04)
[EN] The de-novo synthesis of soluble or solid-supported Pd-(CaCO3)(n) clusters (n = 2-13) and their high catalytic activity for the semi-hydrogenation of internal alkynes compared to terminal alkynes, is presented. ...