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105 K Wide Room Temperature Spin Transition Memory Due to a Supramolecular Latch Mechanism

Seredyuk, Maksym; Znovjyak, Kateryna; Valverde-Muñoz, Francisco Javier; da Silva, Ivan; Muñoz Roca, María Del Carmen; Moroz, Yurii S.; Real, José Antonio (American Chemical Society, 2022-08-10)

[EN] Little is known about the mechanisms behind the bistability (memory) of molecular spin transition compounds over broad temperature ranges (>100 K). To address this point, we report on a new discrete Fe-II neutral ...
Clathration of Five-Membered Aromatic Rings in the Bimetallic Spin Crossover Metal-Organic Framework [Fe(TPT)2/3{MI(CN)2}2]·G (MI = Ag, Au)

Piñeiro Lopez, Lucía; Arcís Castillo, Zulema; Muñoz Roca, María del Carmen; Real, José A. (American Chemical Society, 2014)

Six clathrate compounds of the three-dimensional spin crossover metal−organic framework formulated [Fe(TPT)2/3{MI (CN)2}2]· nG, where TPT is 2,4,6-tris(4-pyridyl)-1,3,5-triazine, MI = Ag or Au and G represent the guest ...
Unprecedented multi-stable spin crossover molecular material with two thermal memory channels

Seredyuk, Maksym; Muñoz Roca, María del Carmen; Castro, Miguel; Romero-Morcillo, Tania; Gaspar, Ana B.; Real, José Antonio (Wiley-VCH Verlag, 2013-05-17)

Two in one: A new iron(II) complex with short alkyl substituents exhibits an unprecedented bimodal behavior governed by the coexistence of three phases: two structurally different low-spin phases and one high-spin phase. ...

Mostrando ítems 1-3 de 3