[EN] Hydrothermally prepared Mo-V-Sb mixed oxides doped with alkali metal cations (Li+, Na+, K+, Rb+, or Cs+) show a significantly improved catalytic behavior in the oxidative dehydrogenation of ethane (ODH) compared to ...
Delgado Muñoz, Daniel; Sanchis, Rut; Solsona Espriu, Benjamin Eduardo; Concepción Heydorn, Patricia; López Nieto, José Manuel(Springer-Verlag, 2020-12)
[EN] A comparative study of the catalytic properties for the oxidation of C2-C3 alkanes and olefins has been carried out over unpromoted and M-promoted NiO catalysts (Me¿=¿K, La, Ce, al, Zr, Sn, Nb). The catalysts have ...
Natesakhawat, Sittichai; Popczun, Eric J.; Baltrus, John P.; Wang, Kun; Serna Merino, Pedro Manuel; Liu, Sophie; Meyer, Randall; Lekse, Jonathan W.(John Wiley & Sons, 2024-06)
[EN] Oxidative dehydrogenation (ODH) of light alkanes to produce C-2-C-3 olefins is a promising alternative to conventional steam cracking. Perovskite oxides are emerging as efficient catalysts for this process due to their ...
[EN] Mechanical stability is a crucial property for the industrial implementation of heterogeneous catalysts and adsorbents. Both particle size and shape need to be investigated for each application where, typically, a ...
Massó Ramírez, Amada; Ivars-Barceló, Francisco; López Nieto, José Manuel(Elsevier, 2020-10-01)
[EN] The investigation here presented studies the effect of the synthesis temperature (from 80 to 110 degrees C) and the time (from 1 to 4 days) employed to precipitate catalyst precursors by reflux method, on the ...
[EN] The robustness of one selected Ni-W-O catalyst has been studied in the oxidative dehydrogenation of ethane. This catalyst initially deactivates for the first 10 h online decreasing 15% of its catalytic activity compared ...
López Nieto, José Manuel; Solsona Espriu, Benjamin Eduardo; Grasselli, Robert K.; Concepción Heydorn, Patricia(Springer Verlag (Germany), 2014-09)
Metal oxide promoted NiO catalysts with a Ni/(Me + Ni) atomic ratio 0.92 have been investigated for the oxidative dehydrogenation of ethane. These materials have been characterized by several techniques (N-2-adsorption, ...
Botella Asuncion, Pablo; Dejoz, A.; Abello, M. C.; Vazquez, M. I.; Arrua, L.; López Nieto, José Manuel(Elsevier, 2009-04-30)
[EN] Mo-V-X (X = Nb, Sb and/or Te) mixed oxides have been prepared by hydrothermal synthesis and heat-treated in N(2) at 450 degrees C or 600 degrees C for 2 h. The calcination temperature and the presence or absence of ...