[EN] C1 chemistry, which is the catalytic transformation of C1 molecules including CO, CO2, CH4, CH3OH, and HCOOH, plays an important role in providing energy and chemical supplies while meeting environmental requirements. ...
[EN] Deep-UV photolysis (either 165 or 185 nm) of surface hydroxy groups leads to homolytic O H bondcleavage with the generation of oxyl radicals that can initiate the room-temperature
radical-chain methane activation. ...
[EN] A series of 2.5% Rh/M@Al2O3 model catalysts were prepared by supporting Rh on high-area gamma-Al2O3, resulting in a surface covered by a monolayer (4.5-7 atoms/nm(2)) of MO promoter oxides (M = Fe, V. Nb, Ta, Ti, Y, ...