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Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study

Beltran, Tomas F.; Feliz Rodriguez, Marta; Llusar, Rosa; Mata, Jose A.; Safont, Vicent S. (American Chemical Society, 2011)

[EN] The catalytic hydrodefluorination (HDF) of pentafluoropyridine in the presence of arylsilanes is catalyzed by the tungsten and molybdenum(IV) cluster hydrides of formula [M3 S4 H3(dmpe)3] ¿, W-1¿for M = W and Mo-1¿for ...
New sandwich and half-sandwich titanium hydrazido compounds

Selby, Jonathan D.; Feliz Rodriguez, Marta; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip (American Chemical Society, 2011)

[EN] New mono- and bis-cyclopentadienyl terminal titanium hydrazido(2-) compounds were prepared by tert-butyl imide/N,N'-disubstituted hydrazine exchange reactions. Reaction of Cp*Ti(N(t)Bu)Cl(PY) (1) with Ph(2)NNH(2) gave ...

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