[EN] The new bimetallic nickel(II) compound (PPh4)4[Ni2(2)]·6H2O (3), where H8[2] stands for N,N',N'',N'''-1,2,4,5-benzene-tetrayltetrakis(oxamic acid), has been synthesized and its crystal structure determined by ...
Lan, W.; Valverde-Muñoz, F.J.; Hao, X.; Dou, Y.; Muñoz Roca, María Del Carmen; Zhou, Z.; Liu, H.; Liu, Q.; Real, J.A.; Zhang, D.(The Royal Society of Chemistry, 2019-04-25)
[EN] Self-assembly of octahedral FeII ions, trans-1,2-bis(4-pyridyl) ethane (bpe) bridging ligands and [Hg(XCN)(4)](2-) (X = S (1), Se (2)) tetrahedral building blocks has afforded a new type of hetero-bimetallic Hg-II-Fe-II ...
Ruiz, R.; Caneschi, A.; Gatteschi, D.; Gaspar, A. B.; Real, J. A.; Fernández, I.; Muñoz Roca, María Del Carmen(Elsevier, 1999-11-01)
[EN] A new manganese(III)-1,10-phenanthroline-5,6-dione (phendione) complex possessing a putative Mn-2(mu-O) (mu-O2CMe)(2) core has been found to undergo a Ligand-based oxidative cleavage of the C(5)-C(6) bond in weak acid ...
[EN] New homo¿ and heterometallic hexanuclear complexes of formula {[Cu(tmen)(H2O)]2[Cu(tmen)]2[Cu2L](H2O)}(ClO4)4 · 2 H2O [Cu6¿tmen] {[Cu(pmdien)]4[Cu2L]}(ClO4)4 · 4 H2O [Cu6¿pmdien] and {[Ni(cyclam)]4[Cu2L]}(ClO4)4 · 4 ...
Ortega-Villar, Norma; Muñoz Roca, María del Carmen; Real, José A.(MDPI, 2016-03)
[EN] This review provides an up to date survey of a singular class of iron(II) spin crossover (SCO)
molecular materials that undergo high-spin (HS) Ø low-spin (LS) phase transitions accompanied
by crystallographic symmetry ...