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Homoleptic Iron(II) Complexes with the Ionogenic Ligand 6,6-Bis(1H-tetrazol-5-yl)-2,2'-bipyridine: Spin Crossover Behavior in a Singular 2D Spin Crossover Coordination Polymer

Seredyuk, Maksym; Piñeiro López, Lucia; Muñoz Roca, María del Carmen; Martínez Casado, Francisco J.; Molnár, Gábor; Rodriguez Velamazan, José Alberto; Bousseksou, Azzedine; Real, José Antonio (American Chemical Society, 2015-08)

Deprotonation of the ionogenic tetradentate ligand 6,6'-bis(1H-tetrazol-5-yl)-2,2'-bipyridine [H(2)bipy(ttr)(2)] in the presence of Fe-II in solution has afforded an anionic mononuclear complex and a neutral two-dimensional ...
Steric-shielding vs sigma-pi orbital interactions in triplet-triplet energy transfer

Andreu Ros, María Inmaculada; Morera Bertomeu, Isabel María; Palumbo, Fabrizio; Sastre Navarro, German Ignacio; Bosca Mayans, Francisco; Miranda Alonso, Miguel Ángel (Royal Society of Chemistry: Chemical Science, 2015)

he influence of non-covalent σ–π orbital interactions on triplet–triplet energy transfer (TTET) through tuning of the donor excitation energy remains basically unexplored. In the present work, we have investigated ...

Mostrando ítems 1-2 de 2