Aldehydes possess relatively high chemical energy, which is the driving force for disproportionation reactions such as Cannizzaro and Tishchenko reactions. Generally, this energy is wasted if aldehydes are transformed into ...
Pulido Junquera, Maria Angeles; Oliver Tomás, Borja; Renz, Michael; Boronat Zaragoza, Mercedes; Corma Canós, Avelino(Wiley-VCH Verlag, 2013)
The ketonic decarboxylation of carboxylic acids has been carried out experimentally and studied theoretically by DFT calculations. In the experiments, monoclinic zirconia was identified as a good catalyst, giving high ...