A new class of biodegradable anionic surfactants with structures based on 5-alkoxymethylfuroate was prepared starting from 5-hydroxymethylfurfural (HMF), through a one-pot-two-steps process which involves the selective ...
Aldehydes possess relatively high chemical energy, which is the driving force for disproportionation reactions such as Cannizzaro and Tishchenko reactions. Generally, this energy is wasted if aldehydes are transformed into ...
Primo Arnau, Ana María; Navalón Oltra, Sergio; Asiri, Abdullah M; García Gómez, Hermenegildo(Wiley, 2015-01-02)
A novel procedure for the preparation of fewlayers boron nitride (BN), either as films or as suspended BN platelets, is presented, based on the pyrolysis of chitosan, which serves both as a matrix to embed ammonium borate ...
[EN] In the present study we have selected three different condensation reactions as model reactions, namely the hydroxylalkylation of anisole by paraformaldehyde to bis(methoxyphenyl)-methane, the Pechmann condensation ...
A two-dimensional zeolite with the topol. of MWW sheets has been obtained by direct synthesis with a combination of two org. structure-directing agents. The resultant material consists of approx. 70 % single and double ...
Segarra Ríos, Jorge(Universitat Politècnica de València, 2018-10-08)
[ES] En la digestión anaeróbica de la biomasa se producen corrientes con una determinada concentración
de ácidos carboxílicos de cadena corta, conocidos industrialmente como ácidos grasos volátiles (AGVs),
como por ejemplo ...
Montero Lanzuela, Eva(Universitat Politècnica de València, 2018-09-26)
[ES] En la actualidad, existe una legislación ambiental muy estricta con respecto al contenido de azufre que pueden contener los combustibles de automoción. La presencia de compuestos de azufre en los combustibles da lugar ...
Salinas Rodríguez, Jorge(Universitat Politècnica de València, 2017-09-13)
The products of the fine chemical industry have become a fundamental need to maintain current social life. Fine chemicals include pharmaceuticals, flavorings, fragrances, etc. It should be noted that many of the processes ...
Blandez Barradas, Juan Francisco; Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley, 2015-09-14)
Graphene oxide promotes the oxidative degradation of -guaiacylglycerol--guaiacyl ether, a lignin model compound, in different solvents including acetonitrile, toluene and water mainly to guaiacol, 2-methoxyquinone, vanillic ...
Pulido Junquera, Maria Angeles; Oliver Tomás, Borja; Renz, Michael; Boronat Zaragoza, Mercedes; Corma Canós, Avelino(Wiley-VCH Verlag, 2013)
The ketonic decarboxylation of carboxylic acids has been carried out experimentally and studied theoretically by DFT calculations. In the experiments, monoclinic zirconia was identified as a good catalyst, giving high ...
[EN] In the last few years, important efforts have been made to synthesize so-called "multipore" zeolites, which contain channels of different dimensions within the same crystalline structure. This is a very attractive ...
Multisite organic inorganic hybrid catalysts have
been prepared and applied in a new general, practical, and
sustainable synthetic procedure toward industrially relevant
GABA derivatives. The domino sequence is composed ...
Primo Arnau, Ana María; Esteve Adell, Iván; Coman, Simona M.; Candu, Natalia; Parvulescu, Vasile; García Gómez, Hermenegildo(Wiley, 2016-01-11)
Pyrolysis of chitosan films containing Au3+ renders 1.1.1 oriented Au nanoplatelets (20 nm lateral size, 3-4 nm height) on a few layers of N-doped graphene ((Lambda) over baru/fl-G), while the lateral sides were 0.0.1 ...
Espinosa López, Juan Carlos; Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley, 2016-08-22)
Natural Sunlight irradiation increases the catalytic activity of reduced graphene oxide (rGO) as metal-free Fenton-like catalyst for phenol degradation. Intermediacy of hydroxyl radicals was proved by electron paramagnetic ...
1,5-Benzothiazepines derivatives were obtained first by starting
from 1,3-diphenylpropenone derivatives (chalcones) and 2-aminothiophenol
by using aluminosilicate solid catalysts. However,
diffusional limitations and ...
[EN] The isomorphic substitution of two different metals (Mg and Co) within the framework of the ITQ-51 zeotype (IFO structure) using bulky aromatic proton sponges as organic structure-directing agents (OSDAs) has allowed ...
Baldovi, Herme G.; Neatu, Stefan; Khan, Anish; Asiri, Abdullah M.; Kosa, Samia A.; García Gómez, Hermenegildo(American Chemical Society, 2015-03-26)
Recent photocatalytic data for CO2 reduction by H2O using simulated sunlight have shown that, while TiO2 Evonik P25 containing Au nanoparticles (NPs; Au/P25) generates considerably higher amounts of hydrogen than methane, ...